Summary
A smooth method of synthesizing 3H, 6H-1,2-dithiolo[4,3-c]1,2-dithiole-3,6-dithione (3), and also its partial desulfuration to yield 3H, 6H-1,2-dithiolo[4,3-c]1,2-dithiole-3-one-6-thione (4) is presented. The ethylation product5 of the monothione4 reacts with various nucleophilic reagents to form remarkably stable adducts. The adducts of5 with methanol,tert-butyl mercaptan, and with aniline could be isolated and characterized by their1H-NMR spectra.
Zusammenfassung
Eine glatte Synthese für 3H,6H-1,2-Dithiolo[4,3-c]1,2-dithiol-3,6-dithion (3) und für dessen partielle Entschwefelung zu 3H,6H-1,2-Dithiolo[4,3-c]1,2-dithiol-3-on-6-thion (4) wird angegeben. Das Ethylierungsprodukt5 des Monothions4 reagiert mit unterschiedlichen Nukleophilen zu bemerkenswert stabilen Addukten. Die Addukte mit Methanol,tert.-Butylmercaptan und mit Anilin wurden isoliert und durch ihr1H-NMR-Spektrum charakterisiert.
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Kordts, B., Richter, A.M. & Fanghänel, E. Addition compounds of nucleophiles and 3-ethylthio-6-oxo-6H-1,2-dithiolo[4,3-c]1,2-dithiolium tetrafluoroborate. Synthesis of 3H,6H-1,2-dithiolo[4,3-c]1,2-dithiole-3-one-6-thione. Monatsh Chem 122, 71–75 (1991). https://doi.org/10.1007/BF00815167
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DOI: https://doi.org/10.1007/BF00815167
Keywords
- 3H, 6H-1,2-Dithiolo[4,3-c]1,2-dithiole-3,6-dithione, synthesis and partial desulfuration of
- 3H, 6H-1,2-Dithiolo[4,3-c]1,2-dithiole-3-one-6-thione, synthesis and alkylation of
- 3-Ethylthio-6-oxo-6H-1,2-dithiolo[4,3-c]1,2-dithiolium tetrafluoroborate, synthesis and formation of adducts with nucleophiles of