Summary
It is shown that the equations derived byVoigt andAbraham for the calculation of salt activities in concentrated solutions are equivalent and that they satisfy theGibbs-Duhem equation.
Zusammenfassung
Es wird gezeigt, daß die vonVoigt undAbraham zur Berechnung der Aktivitäten von Salzen in konzentrierten Lösungen hergeleiteten Gleichungen äquivalent sind und dieGibbs-Duhem-Beziehung erfüllen.
References
Voigt W (1993) Monatsh Chem124: 839–848
Abraham M (1981) J Chim Phys78: 57
Ally MR, Braunstein J (1993) Fluid Phase Equilibria87: 213
Hill TL (1946) Statistical mechanics of multimolecular adsorption I. J Chem Phys 14, 4: 263–267
Dole M (1948) Statistical thermodynamics of the sorption of vapors by solids. Chem Phys14: 25–30
Mayer J, Mayer MG (1940) Statistical Mechanics. John Wiley and Sons, New York, pp 92, 432, 433
Klotz IM (1950) Chemical Thermodynamics. Prentice Hall, New York, p 190
Stokes RH, Robinson R (1948) J Am Chem Soc70: 1870
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Braunstein, J., Ally, M.R. On theAbraham equation for salt activities in concentrated solutions. Monatsh Chem 127, 269–273 (1996). https://doi.org/10.1007/BF00813792
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00813792