Abstract
Whilst there is merit in using NH3 or CO as probes to determine the surface acidity of solid catalysts by thermal and/or spectroscopic means, we show that, following Wakabayashi et al., quantitative spectroscopic changes accompanying the adsorption of dinitrogen offer more reliable assessments. Subtle differences arising from the use of N2 as between CoALPO and zeolitic (aluminosilicate) catalysts are also discussed.
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J. Chen and J.M. Thomas, J. Chem. Soc. Chem. Commun. (1994) 603.
J. Chen, P.A. Wright, J.M. Thomas, S. Natarajan, L. Marchese, S.M. Bradley, G. Sankar, C.R.A. Catlow and P.L. Gai-Boyes, J. Phys. Chem. 98 (1994) 10216.
J.M. Thomas, G.N. Greaves, G. Sankar, P.A. Wright, J. Chen, A.J. Dent and L. Marchese, Angew. Chem. Int. Ed. Engl. 33 (1994) 1871.
L. Marchese, J. Chen, J.M. Thomas, S. Coluccia and A. Zecchina, J. Phys. Chem. 98 (1994) 13350.
U. Lohse, R. Bertram, K. Jancke, I. Kurzawski, B. Parlitz, E. Löffler and E. Schreier, J. Chem. Soc. Faraday Trans. 91 (1995) 1163.
A. Zecchina, S. Bordiga, G. Spoto, D. Scarano, G. Petrini, G. Leofanti, M. Padovan and C. Otero Areàn, J. Chem. Soc. Faraday Trans. 88 (1992) 2959.
L. Marchese, G. Martra, N. Damilano, S. Coluccia and J.M. Thomas, submitted to 11th ICC.
F. Wakabayashi, J. Kondo, A. Wada, K. Domen and C. Hirose, J. Phys. Chem. 97 (1993) 10761.
F. Wakabayashi, J. Kondo, K. Domen and C. Hirose, Catal. Lett. 21 (1993) 257.
F. Geobaldo, C. Lamberti. G. Ricchiardi, S. Bordiga, A. Zecchina, G. Turnes Palomino and C. Otero Arean, J. Phys. Chem., in press.
K.M. Neyman, P. Strodel, S.P. Ruzankin, N. Schiensog, H. Knözinger and N. Rösch, Catal. Lett. 31 (1995) 273.
J. Chen, J.M. Thomas, R.P. Townsend and C.M. Lok, UK Patent Application 93186443 (1993).
L. Marcheseetal., unpublished results.
D. Scarano, A. Zecchina, S. Bordiga, F. Geolbaldo, G. Spoto, G. Petrini, G. Leofanti, M. Padovan and G. Tozzola, J. Chem. Soc. Faraday Trans. 89 (1993)4123.
G.C. Pimentel and A.L. McClellan, in:The Hydrogen Bond (Freeman, San Francisco, 1960).
J. Sauer, P. Ugliengo, E. Garrone and V.R. Saunders, Chem. Rev. 94 (1994) 2095.
M.A. Makarova, A.F. Ojo, K. Karim, M. Hunger and J. Dwyer, J. Phys. Chem. 98 (1994) 3623.
D.D. Saperstein and A.J. Rein, J. Phys. Chem. 81 (1977) 2134.
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Marchese, L., Gianotti, E., Damilano, N. et al. Assessing the BrØnsted acidity of CoAPO-18 catalysts by using N2 as molecular probe. Catal Lett 37, 107–111 (1996). https://doi.org/10.1007/BF00813527
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DOI: https://doi.org/10.1007/BF00813527