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Synthesen in der Isocamphanreihe, 39. Mitt.: Verbesserung derDiels-Alder-Reaktion von Cyclopentadien mit Mesityloxid durch Ultraschall und eine neue Synthese von Dehydrocamphen

Syntheses in the isocamphane series, XXXIX. Improvement of theDiels-Alder reaction of cyclopentadiene with mesityloxide by means of ultrasound and a new synthesis of dehydrocamphene

  • Organische Chemie Und Biochemie
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Summary

The synthesis of the valuable terpenic synthon 2-acetyl-3,3-dimethylbicyclo[2.2.1]hept-5-ene is clearly improved concerning the yield and especially the reaction time by applying ultrasound on theDiels-Alder reaction of cyclopentadiene with mesityl oxide. A new synthesis of dehydrocamphene and its odour impression is described.

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Authors and Affiliations

  1. Institut für Pharmazeutische Chemie, Universität Wien, A-1090, Wien, Österreich

    G. Buchbauer, H. Spreitzer, I. Bauer & H. Knobel

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  1. G. Buchbauer
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  2. H. Spreitzer
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  3. I. Bauer
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  4. H. Knobel
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Buchbauer, G., Spreitzer, H., Bauer, I. et al. Synthesen in der Isocamphanreihe, 39. Mitt.: Verbesserung derDiels-Alder-Reaktion von Cyclopentadien mit Mesityloxid durch Ultraschall und eine neue Synthese von Dehydrocamphen. Monatsh Chem 125, 921–925 (1994). https://doi.org/10.1007/BF00812706

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  • DOI: https://doi.org/10.1007/BF00812706

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