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Polarographic study of Tl+, Li+, Na+, K+, and Cs+ complexes with monensin anion in dipolar aprotic solvents

Polarographische Untersuchung von Tl+-, Li+-, Na+- und Cs+-Komplexen mit Monesin-Anion in dipolaren aprotischen Lösungsmitteln

  • Anorganische Und Physikalische Chemie
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Summary

The stability constants,K sof monensin complexes with Li+, Na+, K+ and Cs+ ions were studied by a competitive polarographic method using the Tl+/Tl(Hg) redox couple as a sensitive electrochemical probe. TheK svalues are strongly influenced by the solvents (acetonitrile, propionitrile, acetone, N,N-dimethylformamide, N-methyl pyrolidinone, N,N-dimethylacetamide, dimethylsulfoxide, N,N-diethylformamide and N,N-diethylacetamide were used in experiments) and vary inversely with the Gutmann donicity scale. Molecular mechanics computations revealed the probable structures of the complexes.

Zusammenfassung

Es wurden die StabilitätskonstantenK svon Monesin-Komplexen mit Li+-, Ma+- und Cs+-Ionen mittels einer competitiven polarographischen Methode unter Verwendung der Tl+/Tl(Hg)-Redoxelektrode als sensitiver elektrochemischer Sonde bestimmt. DieK s-Werte werden stark vom Lösungsmittel (Acetonitril, Propionitril, Aceton, N,N-Dimethylformamid, N-Methylpyrrolidinon, N,N-Dimethylacetamid, Dimethylsulfoxid, N,N-Diethylformamid und N,N-Diethylacetamid) beeinflußt, wobei sie invers zurGutmann schen Donizitätsskala variieren. Die wahrscheinliche Struktur der Komplexe wurde mittels molekularmechanischer Berechnungen ermittelt.

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References

  1. Izatt R. M., Bradshaw J. S., Nielsen S. A., Lamb J. D., Christensen J. J., Sen D. (1985) Chem. Rev.85: 271

    Google Scholar 

  2. Izatt R. M., Pawlak K., Bradshaw J. S., Bruening R. L. (1991) Chem. Rev.91: 1721

    Google Scholar 

  3. Lada E., Kalinowski M. K. (1990) Monatsh. Chem.122: 1

    Google Scholar 

  4. Lada E., Urbanczyk A., Kalinowski M. K. (1990) Austr. J. Chem.43: 2003

    Google Scholar 

  5. Gutmann V. (1978) The donor-acceptor approach to molecular interactions. Plenum Press, New York

    Google Scholar 

  6. Cox B. G., van Truong N., Rzeszotarska J., Schneider H. (1984) J. Chem. Soc., Faraday Trans.I 80: 3275

    Google Scholar 

  7. Taylor R., Kauffman R. F., Pfeifer D. R. (1982) In: Westley J. W. (eds.) Polyeter antibiotics naturally occurring acid ionophores, vol. 1. Dekker, New York

    Google Scholar 

  8. Barrans P. Y., Alleaume M. (1982) Acta Cryst.B 38: 1144

    Google Scholar 

  9. Walba D. M., Hersmeier M., Haltiwanger R. C., Noordik J. H. (1986) J. Org. Chem.51: 245

    Google Scholar 

  10. Bartnicka H., Bojanowska I., Rzeszotarska J., Kalinowski M. K. (1993) J. Chem. Res., (s) 190

  11. Cox B. G., Van Truong N., Rzeszotarska J., Schneider H. (1984) J. Am. Chem. Soc.106: 5965

    Google Scholar 

  12. Mann C. K. (1969) In: Bard A. J. (ed.) Electroanalytical chemistry, vol. 3. M. Dekker, New York, ch. 2

    Google Scholar 

  13. Kemula W., Zawadowska J. (1980) Fresenius Z. Anal. Chem.300: 39

    Google Scholar 

  14. Gritzner G. (1977) Inorg. Chim. Acta24: 5

    Google Scholar 

  15. Luca C., Magearu V., Popa G. (1966) J. Electroanal. Chem.12: 15

    Google Scholar 

  16. Popa G., Magearu V. (1969) J. Electroanal. Chem.22: 85

    Google Scholar 

  17. Yee E. L., Yabib J., Weaver M. J. (1979) J. Electroanal. Chem.95: 241

    Google Scholar 

  18. Semnani A., Shamsipur M. (1991) J. Electroanal. Chem.315: 95

    Google Scholar 

  19. Ladd M. F. C. (1968) Theoret. Chim. Acta12: 333

    Google Scholar 

  20. Kollman P. A. (1985) Acc. Chem. Res.18: 105

    Google Scholar 

  21. Frubeis H., Klein R., Wallmeier H. (1987) Angew. Chem.99: 413

    Google Scholar 

  22. Brubaker G. R., Johnson D. W. (1984) Coord. Chem. Rev.53: 1

    Google Scholar 

  23. Litson S., Felder C. E., Shanzer A., Libman J. (1987) In: Izatt R. M., Christensen J. J. (eds.) Synthesis of macrocycles. The design of selective complexing agents. Progress in macrocyclic chemistry, vol. 3. Wiley-Interscience, New York, pp. 241–307

    Google Scholar 

  24. Hancock R. D. (1989) Progr. Inorg. Chem.37: 187

    Google Scholar 

  25. Hancock R. D., Martell A. E. (1989) Chem. Rev.89: 1875

    Google Scholar 

  26. Weiner S. J., Kollman P. A., Case D. A., Singh U. C., Ghio C., Alagona G., Profeta S., Jr., Weiner P. K. (1984) J. Am. Chem. Soc.106: 765

    Google Scholar 

  27. Weiner S. J., Kollman P. A., Nguyen D. T., Case D. A. (1986) J. Comput. Chem.7: 230

    Google Scholar 

  28. Singh U. C., Weiner P. K., Caldwell J., Kollman P. A. (1987) AMBER 3.0. University of California, San Francisco

    Google Scholar 

  29. Grootenhuis P. D. J., Kollman P. A. (1989) J. Am. Chem. Soc.111: 2152

    Google Scholar 

  30. Besler P. H., Merz K. M., Jr., Kollman P. A. (1990) J. Comput. Chem.11: 431

    Google Scholar 

  31. Merz K. M., Jr. (1992) J. Comput. Chem.13: 749

    Google Scholar 

  32. Connoly M. L. (1983) J. Appl. Cryst.16: 548

    Google Scholar 

  33. Dewar M. J. S., Thiel W. (1977) J. Am. Chem. Soc.99: 4899

    Google Scholar 

  34. Dewar M. J. S., Thiel W. (1977) J. Am. Chem. Soc.99: 4907

    Google Scholar 

  35. Dewar M. J. S., McKee M. L., Rzepa H. S. (1978) J. Am. Chem. Soc.100: 3607

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Warsaw, PL 02-093, Warszawa, Poland

    S. Filipek, J. Rzeszotarska & M. K. Kalinowski

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  1. S. Filipek
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  2. J. Rzeszotarska
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  3. M. K. Kalinowski
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Filipek, S., Rzeszotarska, J. & Kalinowski, M.K. Polarographic study of Tl+, Li+, Na+, K+, and Cs+ complexes with monensin anion in dipolar aprotic solvents. Monatsh Chem 125, 801–809 (1994). https://doi.org/10.1007/BF00812692

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