Abstract
Nickel metal introduced into Y-zeolite exhibited a high catalytic activity in the dehydro-genation of methane and in the hydrogenation of carbon dioxide with methane to obtain hydrogen and CO at about 850 K. The activity strongly depended on the nickel amount in NaY, and the catalytic properties were influenced by the kind of cations in the Y-zeolite. The higher CO2 conversion was obtained over Ni supported on non-acidic zeolites.
Similar content being viewed by others
References
J.R. Rostrup-Nielsen, in:Catalysis, Vol. 5, eds. J.R. Anderson and M. Boudart (Springer, Berlin, 1984) p. 1.
J.R. Rostrup-Nielsen, in:Methane Conversion, eds. D.M. Bibby, C.D. Chang, R.F. Howe and S. Yurchak (Eisevier, Amsterdam, 1988) p. 73.
J. Nakamura, S. Umeda, K. Kubushiro, T. Ohashi, K. Kunimori and T. Uchijima, Shokubai (Catalyst) 33 (1991) 99.
G.J. Kim, S.J. Jung, T.J. Kim and L.M. Kwon, J. Korean Inst. Chem. Eng. (Hwahak Konghak) 25 (1987) 477.
M.A. Vannice, J. Catal. 44 (1976) 152.
S. Bhatia, J.M. Mathews and N.N. Bakhshi, Can. J. Chem. Eng. 56 (1978) 575.
T. Baba, G.J. Kim and Y. Ono, J. Chem. Soc. Faraday Trans. 88 (1992) 891.
S.J. Tauster, S.C. Fung and R.L. Garten, J. Am. Chem. Soc. 4 (1978) 170.
C.P. Huang and J.T. Richardson, J. Catal. 51 (1978) 1.
R.A. Della Betta and M. Boudart, in:Proc. 5th Int. Congr. on Catalysis (Eisevier, Amsterdam, 1973) p. 1329.
J.W. Ward, in:Zeolite Chemistry and Catalysis, ed. J.A. Rabo, ACS Mono. 171 (Am. Chem. Soc., Washington, 1976) p. 118.
J.W. Ward, J. Catal. 10 (1968) 34.
D.S. Park, J.R. Lee and J.T. Kim, J. Korean Inst. Chem. Eng. (Hwahak Konghak) 27 (1989) 723.
G.N. Sauvion, M.F. Guillex, J.F. Tempere and D. Delafosse, in:Metal Microstructure in Zeolite, Studies in Surface Science and Catalysis, Vol. 12, eds. P.A. Jacobs, N.I. Jaeger, P. Jiru and G. Schulz-Ekloff (Elsevier, Amsterdam, 1982) p. 229.
G.A. Martin, M. Primet and J.A. Dalmon, J. Catal. 53 (1978) 321.
J.A. Dalmon and G.A. Martin, J. Chem. Soc. Faraday Trans. 10 (1979) 11.
S. Fujita, H. Terunuma, M. Nakamura and N. Takezawa, Ind. Eng. Chem. Res. 30 (1991) 146.
C.N. Satterfield,Heterogeneous Catalysis in Practice (McGraw-Hill, New York, 1980) p. 280.
A.B. Anderson, J. Am. Chem. Soc. 99 (1977) 696.
B. Kneale and J.R.H. Ross, Faraday Trans. I 79 (1983) 157.
J.G. McCarty and H. Wise, J. Catal. 57 (1979) 406.
S.M. Davis, F. Zaera and G. Somorjai, J. Catal. 77 (1982) 439.
C.A. Bernardo and D.L. Trimm, Carbon 17 (1979) 115.
J.L. Falconer and A.E. Zagli, J. Catal. 62 (1980) 280.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kim, G.J., Cho, DS., Kim, KH. et al. The reaction of CO2 with CH4 to synthesize H2 and CO over nickel-loaded Y-zeolites. Catal Lett 28, 41–52 (1994). https://doi.org/10.1007/BF00812468
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00812468