Summary
Several substituted crowned phenoselenazin-16-one derivatives were prepared by condensation of substituted zinc 2-amino-benzeneselenolates with 1,4-quinone of benzo[15]crown-5 or its dibromide in alcoholic solution. The dehalogenation of the bromoselenazinones was also investigated.
Zusammenfassung
Es wurden einige substituierte Kronen-Phenoselenazin-16-on-Derivate mittels Kondensation von substituierten Zink-2-aminobenzolselenolaten mit dem 1,4-Chinon von Benzo[15]krone-5 oder seinem Dibromid in alkoholischer Lösung dargestellt. Die Dehalogenierung der Bromselenazinone wurde ebenfalls untersucht.
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Iqbal, N., Ueno, Y. The synthesis of crowned phenoselenazinone derivatives. Monatsh Chem 123, 849–852 (1992). https://doi.org/10.1007/BF00812334
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DOI: https://doi.org/10.1007/BF00812334
Keywords
- 16H-2,5,8,11,14-Pentaoxacyclopentadecano[2,3-a]phenoselenazin-16-one
- 20-Chloro-16H-2,5,8,11,14-pentaoxacyclopentadecano[2,3-a]phenoselenazin-16-one
- 17-Bromo-16H-2,5,8,11,14-pentaoxacyclopentadecano[2,3-a]phenoselenazin-16-one
- 20-Chloro-17-bromo-16H-2,5,8,11,14-pentaoxacyclopentadecano[2,3-a]phenoselenazin-16-one