Monatshefte für Chemie / Chemical Monthly

, Volume 123, Issue 8–9, pp 709–711 | Cite as

Influence of tetraalkylammonium ions on structure of nonaqueous solvents

Short communication
  • Adela Kotočová
Anorganische Und Physikalische Chemie
  • 22 Downloads

Summary

The half-wave potentials of the redox system [Co(en)3]3+/[Co(en)3]2+ have been influenced by the tetraalkylamonium cation of the supporting electrolyte used. This was explained with the specific interactions (solvation) of the tetraalkylamonium ion with the nonaqueous solvent.

Keywords

Solvation of tetraalkylammonium ions Half-wave potential Thermodynamics Nonaqueous solvents 

Einfluß von Tetraalkylammoniumionen auf die Struktur nichtwäßriger Lösungsmittel (Kurze Mitt.)

Zusammenfassung

Das Halbwellenpotential des Redoxsystems [Co(en)3]3+/[Co(en)3]2+ wird von Tetraalkylammonium-Ionen des Stützelektrolyten beeinflußt. Dies wird durch die spezifischen Wechselwirkungen (Solvatation) der Ionen mit dem nichtwäßrigen Lösungsmittel erklärt.

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Copyright information

© Springer-Verlag 1992

Authors and Affiliations

  • Adela Kotočová
    • 1
  1. 1.Department of Inorganic ChemistrySlovak Technical UniversityBratislavaCzechoslovakia

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