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Monatshefte für Chemie / Chemical Monthly

, Volume 125, Issue 4, pp 385–394 | Cite as

Cr(III), Fe(III), and Co(II) complexes of tetraazamacrocycles derived from 2,3-butanedione or benzil and 1,8-diamino-3,6-diazaoctane

  • P. K. Rai
  • R. N. Prasad
Anorganische Und Physikalische Chemie

Summary

Template condensation of α-diketones such as 2,3-butanedione or benzil with 1,8-diamino-3,6-diazaoctane in the presence of Cr(III), Fe(III) and Co(II) results in the formation of macrocyclic complexes of the type [MLX2]X and [CoLX]X (where M=Cr(III), Fe(III), L=N4 macrocycle and X=NO 3 or Cl). The complexes have been characterized by elemental analyses, conductance and magnetic measurements, molecular weight determinations, infrared and diffuse reflectance spectral studies.

Keywords

Tetraazamacrocycles Cr(III), Fe(III) and Co(II) Complexes Magnetic measurements Diffuse reflectance spectra 

Cr(III)-, Fe(III)- und Co(II)-Komplexe mit Tetraazamacrocyclen aus 2,3-Butandion oder Benzil und 1,8-Diamino-3,6-diazaoctan

Zusammenfassung

Kondensation von α-Diketonenen wie 2,3-Butandion oder Benzil mit 1,8-Diamino-3,6-diazaoctan in Gegenwart von Cr(III), Fe(III) und Co(II) resultiert in der Bildung von macrocyclischen Komplexen vom Typ [MLX2]X und [CoLX]X mit M=Cr(III), Fe(III), L=N4-Macrocyclus und X=NO 3 oder Cl. Die Komplexe wurden mittels Elementaranalyse, Leitfähigkeits-und magnetischen Messungen, Molekulargewichtsbestimmung und Infrarot- bzw. diffuser Reflexions-Spektren charakterisiert.

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Copyright information

© Springer-Verlag 1994

Authors and Affiliations

  • P. K. Rai
    • 1
  • R. N. Prasad
    • 1
  1. 1.Department of ChemistryUniversity of RajasthanJaipurIndia

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