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A novel reaction of 11,11,12,12-tetracyanoanthraquinodimethane: The formation of 10-dicyanomethylene-anthrone hydrazone

Eine neue Reaktion von 11,11,12,12-Tetracyanoanthrachinodimethan: die Bildung von 10-Dicyanomethylen-anthronhydrazon (Kurze Mitt.)

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  • Organische Chemie Und Biochemie
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Summary

A novel reaction of 11,11,12,12-tetracyanoanthraquinodimethane — its transformation into 10-dicyanomethylene-anthrone hydrazone by reaction with hydrazine — is reported. This hydrazone seems to be a convenient starting material in the synthesis of anthracene derivatives and compounds incorporating anthracenic fragments, but is itself as a conjugated donor acceptor system a material with interesting physical properties.

Zusammenfassung

Eine neue Reaktion von 11,11,12,12-Tetracyanoanthrachinodimethan — seine Umsetzung zum 10-Dicyanomethylen-anthronhydrazon durch Reaktion mit Hydrazin — wird beschrieben. Dieses Hydrazon könnte als Ausgangsmaterial für die Synthese von Anthracenderivaten dienen, zeigt aber auch selbst als konjugiertes Donor-Akzeptorsystem interessante physikalische Eigenschaften.

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Authors and Affiliations

  1. Institut für Chemie, Johannes-Kepler-Universität, A-4040, Linz, Austria

    H. Falk & A. F. Vaisburg

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  1. H. Falk
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  2. A. F. Vaisburg
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Falk, H., Vaisburg, A.F. A novel reaction of 11,11,12,12-tetracyanoanthraquinodimethane: The formation of 10-dicyanomethylene-anthrone hydrazone. Monatsh Chem 125, 549–551 (1994). https://doi.org/10.1007/BF00811847

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  • DOI: https://doi.org/10.1007/BF00811847

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