Summary
Stability constants and composition of cadmium-glycinate binary complexes were determined using cyclic voltammetry. Furthermore, binary and ternary complex equilibria for chloroacetates and glycinate with cadmium in 0.1M aqueous KNO3 atpH 10.4 and 298 K were investigated. Cadmium forms binary complexes with chloroacetates of low stability and ternary ones with chloroacetate-glycinate of significant stability.
Zusammenfassung
Gleichgewichtskonstanten und Zusammensetzung binärer Cadmium-Glycinat-Komplexe wurden mittels zyklischer Voltammetrie bestimmt. Weiters wurden binäre und ternäre Gleichgewichte von Chloroacetaten und Glycinat mit Cadmium in 0.1M KNO3 beipH 10.4 und 298 K untersucht. Cadmium bildet binäre Komplexe geringer Stabilität mit Chloroacetaten und ternäre Komplexe von beträchtlicher Stabilität mit Chloroacetaten und Glycinat.
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Abdel-Hamid, R., Rabia, M.K.M. Equilibria in aqueous cadmium-chloroacetate-glycinate systems. A convolution-deconvolution cyclic voltammetric study. Monatsh Chem 125, 1041–1048 (1994). https://doi.org/10.1007/BF00811511
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DOI: https://doi.org/10.1007/BF00811511