Summary
Cadmium(II) complexes of the type [CdL] (NO3)2 (whereL = tetraazamacrocycle with a 12 to 32-membered ring) have been synthesized by the reactions of 2,3-butanedione or benzil with different aliphatic diamines viz. ethylenediamine, 1,3-diaminopropane, 1,4-diaminobutane, 1,6-diaminohexane, 1,8-diaminooctane and 1,12-diaminododecane in the presence of Cd(II) as template. These complexes have been characterized by elemental analyses, conductivity measurements and IR and NMR spectral studies.
Zusammenfassung
Es wurden Cadmium(II)-Komplexe des Typs [CdL] (NO3)2 (wobeiL einen 12-bis 32-gliedrigen Tetraazamacrocyclus darstellt) mittels der Reaktion von 2,3-Butandion oder Benzil mit verschiedenen aliphatischen Diaminen (Ethylendiamin, 1,3-Diaminopropan, 1,4-Diaminobutan, 1,6-Diaminohexan, 1,8-Diaminooctan und 1,12-Diaminododecan) hergestellt. Die Komplexe wurden mittels Elementaranalyse, Leitfähigkeitsmessungen und Infrarot- bzw. Kernresonanzspektroskopie charakterisiert.
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References
Busch D. H., Farmery K., Goedken V., Katovic C., Melnyk A. C., Sperati C. R., Tokel N. (1971) Adv. Chem. Ser.44: 100
Sessler J. L., Murai T., Lynch W., Cry M. (1988) J. Am. Chem. Soc.110: 5586
Lewis J., Donoghue T. D. O. (1980) J. Chem. Soc. Dalton Trans.1980: 743
Tsintsadze M. G., Tsivadge A. Y., Lebedev O. L., Markova T. M. (1987) Zh. Neorg. Khim.32: 700
Alcock N. W., Curzon E. H., Moore P. (1984) J. Chem. Soc. Dalton Trans.1984: 2813
Drew M. G. B., Cabral J. de O., Cabral M. F., Esho S. F., Nelson S. M. (1979) J. Chem. Soc. Chem. Commun.1979: 1033
Baldwin D. A., Pfeiffer R. M., Reichgott D. W., Rose N. (1973) J. Am. Chem. Soc.95: 5152
Jackels S. C., Farmery K., Barefield E. K., Rose N. J., Busch D. H. (1972) Inorg. Chem.11: 2893
Gagne R. R., Allison J. L., Ingle D. M. (1979) Inorg. Chem.18: 2767
Welsh W. A., Reynolds G. J., Henry P. M. (1977) Inorg. Chem.16: 2558
Bhoon Y. K., Singh R. P. (1981) J. Inorg. Nucl. Chem.43: 1685
Coltrain B. K., Jackels S. C. (1981) Inorg. Chem.20: 2032
Drew M. G. B., Nelson S. M., McCann M., Stevenson C. (1979) J. Chem. Soc. Dalton Trans.1979: 1477
Cabral J., Cabral M. F., Cummins W. J., Drew M. G. B., Rodgers A., Nelson S. M. (1978) Inorg. Chim. Acta30: L313
Jackels S. C., Ciavola J., Carter R. C., Cheek P. L., Pascarelli T. D. (1983) Inorg. Chem.22: 3956
Adams H., Bailey N. A., Fenton D. E., Good R. J., Moody R., Barbarin C. O. R. de (1987) J. Chem. Soc. Dalton Trans.1987: 207
Alcock N. W., Curzon E. H., Herron N., Moore P. (1979) J. Chem. Soc. Dalton Trans.1979: 1987
Ferraro J. R. (1971) Low Frequency Vibration of Inorganic and Coordination Compounds. Plenum Press, New York
Nakamoto K. (1970) Infrared Spectra of Inorganic and Coordination Compounds. Wiley-Interscience, New York
Lewis J., Donoghue T. D. O., Raithby P. R. (1980) J. Chem. Soc. Dalton Trans.1980: 1380
Handbook of Proton-NMR Spectra and Data, Vol. 1. Academic Press, New York, 1985, p. 116
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Prasad, R.N., Parihar, D.S. Complexes of a new series of α-diimine macrocycles, I: Template synthesis of cadmium(II) complexes of tetraazamacrocycles derived from 2,3-butanedione or benzil. Monatsh Chem 122, 683–689 (1991). https://doi.org/10.1007/BF00811467
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DOI: https://doi.org/10.1007/BF00811467