Abstract
Several ring-substituted α-azidocinnamic and β-heterocyclic α-azidoacrylic esters are subject to cathodic reduction under aprotic and protic conditions. Good to excellent yields of rather labile dehydroaminoacid derivatives resp. stableN,N-diacylated enaminoesters are selectively obtainable. The compounds are characterised by spectroscopic methods (1H-NMR, IR, MS).
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Knittel D., Monatsh. Chem.115, 1335 (1984).
Lund H.,Degrand Ch., Tetrahedron Lett.1977, 3593.
Knittel D., Monatsh. Chem.115, 523 (1984).
Knittel D., unveröffentlicht.
Shin Ch., Yonezawa Y., Unoki K., Yoshimura J., Bull. Chem. Soc. Japan52, 1675 (1979); Chem. Lett.1976, 1095.
Hemetsberger H., Knittel S., Weidmann H., Monatsh. Chem.100, 1599 (1969);Knittel D., Synthesis, im Druck.
Knittel D., Henning A., Monatsh. Chem.115, 391 (1984).
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Knittel, D. Elektrolyse substituierter Azidozimtsäure- und Azidoacrylsäureester. Monatsh Chem 116, 1133–1140 (1985). https://doi.org/10.1007/BF00811247
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DOI: https://doi.org/10.1007/BF00811247