Abstract
The stretching force constant correlates satisfactorily with theWiberg's bond order,K(N-O)=11.791 [p(N-O)]−9.565, with a correlation coefficient of 0.958, for nitrogen—oxygen systems.
Zusammenfassung
Die KraftkonstanteK der Streckschwingung läßt sich in befriedigender Weise mit derWibergschen Bindungsordnungp korrelieren:K(N-O)=11.791 [p(N-O)]-9.565. Für Stickstoff-Sauerstoff-Systeme beträgt der Korrelationskoeffizient 0.958.
References
Hase Y., Bull. Soc. Chim. Belg., in press.
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Wiberg K. B., Tetrahedron24, 1083 (1968).
Dewar M. J. S., Thiel W., J. Amer. Chem. Soc.99, 4899 (1977);Thiel W., QCPE10, 353 (1978).
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Hase, Y. Empirical correlation between the stretching force constant and the bond order for nitrogen-oxygen systems. Monatsh Chem 116, 1305–1307 (1985). https://doi.org/10.1007/BF00811101
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DOI: https://doi.org/10.1007/BF00811101