Abstract
Copper, nickel and aluminium derivatives of tetra-2,3-anthratetraazaporphin bearing different substituents in the anthracen part have been prepared. The absorption spectra of these substances in different solvents are given and compared with metal complexes of other linearly annellated tetraazaporphins. In the series of vanadyl complexes of tetraazaporphin (λmax 597 nm), tetra-[1,2-(4-tert-butyl)-benzo]-tetraazaporphin (λmax 698 nm), tetra-[2,3-(6-tert-butyl)-naphtho]-tetraazaporphin (λmax 807 nm), tetra-2,3-(anthra)-tetraazaporphin (λmax 932 nm), tetra-2,3-(tetraceno)-tetraazaporphin (λmax 1055 nm), the absorption maxima of the Q-band are shifted per annellated benzene ring about 100 nm to longer wave lengths.
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Literatur
Moser F. H., Thomas A. L., Phthalocyanine Compounds, Monograph No. 157. Washington, D.C.: American Chemical Society. 1963.
Kugel R., Svirmickas A., Katz J. J., Hindman J. C., Optics Commun.23, 189 (1977).
Behret H., Sandsteda G., Scheren G. G., Ber. Bunsenges. Phys. Chem.84, 1031 (1980).
Tanno T., Woehrle D., Kaneko M., Yamada A., Ber. Bunsenges. Phys. Chem.84, 1032 (1980).
Rieke P. C., Linkous C. L., Armstrong N. R., J. Phys. Chem.88, 1351 (1984).
Armstrong N. R., in: Chemically Modified Surfaces in Catalysis and Electrocatalysis (Miller J. S., ed.). Washington, D.C.: American Chemical Society. 1982; ACS Symp. Ser., No. 192, S. 205–221.
Hanack M., Seelig F. F., Strähle J., Z. Naturforsch.A 34, 983 (1979).
Gouterman M., in: The Porphyrins (Dolphin D., ed.), Vol. III, S. 1. New York: Academic Press. 1978.
Marks T. J., Stojakovic D. R., J. Amer. Chem. Soc.100, 1695 (1978).
Davison J. B., Wynne K. J., Macromolecules11, 186 (1978).
Freyer W.,Minh le quoc, J. Prakt. Chem., in Druck.
Kopranenkov V. N., Gonsarova L. S., Lukjanec E. A., Ž. obšč. Chim.47, 2143 (1975).
Gundermann K.-D.,Klockenbring G.,Röker C.,Brinkmeyer H., Liebigs Ann. Chem.1976, 1873.
Kovšev E. J., Pucnova V. A., Lukjanec E. A., Ž org. Chim.7, 369 (1971).
Michalenko S. A., Barkanova S. V., Lebedev O. L., Lukjanec E. A., Ž. obšč. Chim.41, 2735 (1971).
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Freyer, W., Minh, L.q. Synthese von Metallkomplexen des Tetra-(2,3-anthra)-tetraazaporphins und Vergleich ihrer Elektronenabsorptionsspektren mit denen anderer anellierter Tetraazaporphinsysteme. Monatsh Chem 117, 475–489 (1986). https://doi.org/10.1007/BF00810897
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DOI: https://doi.org/10.1007/BF00810897