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Chromatographic determination of solubility of low soluble substances the physico-chemical basis

Chromatographische Bestimmung der Löslichkeit von schwerlöslichen Substanzen. Die physikalisch-chemische Basis (Kurze Mitteilung)

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  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The physico-chemical basis for a direct chromatographic determination of solubility of low soluble substances by means of adsorption and partition TLC is discussed. This method is a practical consequence of the chromatographic “binary solutions” model, a new semi-empirical approach based on phenomenological thermodynamics.

Zusammenfassung

Die physikalisch-chemische Basis einer direkten chromatographischen Bestimmung der Löslichkeit von schwerlöslichen Substanzen mit Hilfe der Adsorptions- und Verteilungsdünnschichtchromatographie wird diskutiert. Die Möglichkeit einer solchen Bestimmung ist die praktische Konsequenz des chromatographischen Modells der „binären Lösungen”, einer neuen semiempirischen, auf der phänomenologischen Thermodynamik begründeten Methode.

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Authors and Affiliations

  1. Institute of Chemistry, Silesian University, PL-40-006, Katowice, Poland

    Teresa Kowalska

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  1. Teresa Kowalska
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Kowalska, T. Chromatographic determination of solubility of low soluble substances the physico-chemical basis. Monatsh Chem 117, 471–474 (1986). https://doi.org/10.1007/BF00810896

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  • DOI: https://doi.org/10.1007/BF00810896

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