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Zwei neue Oxopalladate: BaPdNd2O5 und BaPdSm2O5 mit planar koordinierten Pd2+-Ionen

New oxocompounds with planar coordinated Pd2+ BaPdNd2O5 and BaPdSm2O5

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Single crystals of BaPdNd2O5 (A), BaPdSm2O5 (B) and BaCuNd2O5 (C) were prepared by solid state reaction using BaCl2 as a fusing assistant (A, B) or by high temperature Laser technique (C). X-ray investigations show tetragonal symmetry with A:a=6.7387 (5),c=5.9002 (25) Å, B:a=6.6667 (13),c=5.8800 (6) Å (space group D 54h −P4/mbm,Z=2). The formerly investigated compound (C) is refined here by single crystal data. (A) and (B) belong to the BaPtNd2O5-type. The results are discussed.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, D-2300, Kiel, Bundesrepublik Deutschland

    Stephan Schiffler & Hanskarl Müller-Buschbaum

Authors
  1. Stephan Schiffler
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  2. Hanskarl Müller-Buschbaum
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Schiffler, S., Müller-Buschbaum, H. Zwei neue Oxopalladate: BaPdNd2O5 und BaPdSm2O5 mit planar koordinierten Pd2+-Ionen. Monatsh Chem 117, 465–470 (1986). https://doi.org/10.1007/BF00810895

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  • DOI: https://doi.org/10.1007/BF00810895

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