Skip to main content
SpringerLink
Log in

Complex formation studies on Ho(III) and Lu(III) with 1-(2-pyridylazo)-2-naphthol (PAN) in alcohol-water solutions

Untersuchungen zur Komplexbildung von Ho(III) und Lu(III) mit 1-(2-Pyridylazo)-2-naphthol (PAN) in alkoholisch-;wä\rigen Lösungen

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The formation ofPAN complexes in the systemsLn(III)—PAN—alcohol-water (where:Ln(III)=Ho, Lu and alcohol=ethanol,n-propanol,iso-propanol) was investigated by a spectrophotometric method. Equilibrium constants for the reactionLn 3+ + HL⇌LnL 2+ + H+ (HL=PAN) and stability constants of complexesLnL 2+ were calculated.

Zusammenfassung

Die Bildung der Komplexe vonPAN in den SystemenLn(III)—PAN—Alkohol-Wasser (Ln(III)=Ho, Lu; Alkohol=Ethanol,n-Propanol,iso-Propanol) wurde mit einer spektrophotometrischen Methode untersucht. Die Gleichgewichtskonstanten der ReaktionenLn 3+ + HL⇌LnL 2+ + H+ (HL==PAN) und die Stabilitätskonstanten der KomplexeLnL 2+ wurden berechnet.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Malinowska A., Czakis-Sulikowska D. M., Polish. J. Chem.55, 963 (1981).

    Google Scholar 

  2. Czakis-Sulikowska D. M.,Malinowska A., Acta Chim. Hung. (in press).

  3. Welcher F. J., Analityczne zastosowanie kwasu wersenowego. Warszawa: WNT. 1963.

    Google Scholar 

  4. Modrzejewski B., PomiarypH. Warszawa: PWN. 1971.

    Google Scholar 

  5. Bates R. G., Determination ofpH. Theory and practice. New York: Wiley. 1964.

    Google Scholar 

  6. Van Uitert L. G., Haas C. G., J. Amer. Chem. Soc.75, 451 (1953).

    Google Scholar 

  7. Asmus E., Z. Anal. Chem.178, 104 (1960);Klausen K. S., Langmyhr F. J., Anal. Chim. Acta28, 501 (1963);Home A., Langmyhr F. J., ibid.36, 383 (1966).

    Google Scholar 

  8. Watters J. I., Langhrem D., J. Amer. Chem. Soc.75, 4819 (1953).

    Google Scholar 

  9. Ivanov V. M., Busiev A. I., Erszova N. S., Zh. Anal. Khim.28, 214 (1973).

    Google Scholar 

  10. Åkerföf G., J. Amer. Chem. Soc.54, 4123 (1932).

    Google Scholar 

  11. Yatsimirskii K. B., Davidenko N. K., Coord. Chem. Rev.27, 223 (1979).

    Google Scholar 

  12. Batajev I. M., Langinova N. M., Privalova T. A., Zh. Neorg. Khim.20, 2358 (1973).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of General Chemistry, Technical University, PL-90924, Łódź, Poland

    Danuta M. Czakis-Sulikowska & Anna Malinowska

Authors
  1. Danuta M. Czakis-Sulikowska
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Anna Malinowska
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Czakis-Sulikowska, D.M., Malinowska, A. Complex formation studies on Ho(III) and Lu(III) with 1-(2-pyridylazo)-2-naphthol (PAN) in alcohol-water solutions. Monatsh Chem 117, 437–441 (1986). https://doi.org/10.1007/BF00810891

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00810891

Keywords

Search

Navigation