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Spektroskopische Untersuchungen an organischen Carbonylverbindungen, 5. Mitt.: Zum Einfluß des π-Chromophors auf das elektronische Spektralverhalten von dimethylaminophenyl-substituierten β-Diketonen bei Kettenverlängerung und Variation der Arylsubstituenten

Spectroscopic studies on organic carbonyl compounds, V: On the influence of the π-chromophore upon the electronic spectral behaviour of dimethylaminophenyl-substituted β-diketones due to chain lengthening and the variation of aryl substituents

  • Organische Chemie Und Biochemie
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Summary

Absorption and fluorescence data of dimethylaminophenyl-substituted β-dicarbonyl compounds are discussed in dependence on the size of the π-electronic system. The variation of the chain length and of the aryl moiety shows the strong influence of the intramolecular donor-acceptor properties on the deactivation processes. The stabilization of the S1-state in polar solvents gives rise to fluorescences with large Stokes shifts.

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Literatur

  1. Welters R., Gehlhaus J., Moeschl G. (1975) Patentschrift DE 2544180

  2. Ilge H. D., Faßler D., Hartmann H. (1984) Z. Chem.24: 218; Hartmann H., Hultzsch R., Ilge H. D., Friedrich B., Hebenstreit J., Faßler D., Meinel U. (1984) Patentschrift DD 225884

    Google Scholar 

  3. Pabon H. J. J. (1964) Recueil Trav. Chim. Pays-Bas83: 379; Pedersen U., Rasmussen P. B., Lawesson S. O. (1985) Liebigs Ann. Chem.1985: 1557; Mann G., Beyer L., Arrieta A. (1987) Z. Chem.27: 172

    Google Scholar 

  4. Gustav K., Bartsch U. (1988) Z. Chem.28: 444; Gustav K., Bartsch U. (1989) Z. Chem.29: 68

    Google Scholar 

  5. Lang G., Malaval A. (1982) Patentschrift BE 889869

  6. Staab H. A. (1962) Einführung in die theoretische organische Chemie, 3. Aufl. Verlag Chemie, Weinheim

    Google Scholar 

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Friedrich-Schiller-Universität Jena, D-O-6900, Jena, Bundesrepublik Deutschland

    Klaus Gustav & Ulrich Bartsch

Authors
  1. Klaus Gustav
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  2. Ulrich Bartsch
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Gustav, K., Bartsch, U. Spektroskopische Untersuchungen an organischen Carbonylverbindungen, 5. Mitt.: Zum Einfluß des π-Chromophors auf das elektronische Spektralverhalten von dimethylaminophenyl-substituierten β-Diketonen bei Kettenverlängerung und Variation der Arylsubstituenten. Monatsh Chem 122, 269–274 (1991). https://doi.org/10.1007/BF00810827

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  • DOI: https://doi.org/10.1007/BF00810827

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