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Study of complexation in the Nd3+-SCN− system

Untersuchungen zur Komplexierung im Nd3+-SCN−-System

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

A spectroscopic study of the association in the Nd3+-SCN− system is presented. A characteristic change of the molar absorptivity of the solution with a plateau at 2–4M [SCN−] and an increase at 4–8M [SCN−] reflects the change from outer- to innersphere complexation.

Zusammenfassung

Es wird eine spektroskopische Studie der Assioziationsverhältnisse im Nd3+-SCN−-System präsentiert. Die charakteristische Änderung in der molaren Absorption der Lösung mit einem Plateau bei 2–4M [SCN−] und ein Anstieg bei 4–8M [SCN−] ist auf einen Wechsel von außensphärischer zu innensphärischer Komplexierung zurückzuführen.

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References

  1. Krejzler J. (1983) Doctoral Thesis. Institute of Nuclear Research, Warsaw

    Google Scholar 

  2. Moor F. L. (1964) Anal. Chem.36: 2158

    Google Scholar 

  3. Gerontopulos P. T., Rigali L., Barbano P. G. (1965) Radiochim. Acta4: 75

    Google Scholar 

  4. Barbano D. G., Rigali L. (1967) J. Chromatogr.29: 303

    Google Scholar 

  5. Huff E. A. (1967) J. Chromatogr.27: 229

    Google Scholar 

  6. Ceccaroli B., Alstad J. (1981) J. Inorg. Nucl. Chem.43: 1881

    Google Scholar 

  7. Khopkar P. K., Mathur J. N. (1974) J. Inorg. Nucl. Chem.36: 3819

    Google Scholar 

  8. Rao C. L., Shahani C. J., Mathew K. A. (1958) Inorg. Nucl. Chem. Lett.4: 655

    Google Scholar 

  9. Sekine T. (1965) Acta Chem. Scand.19: 1519

    Google Scholar 

  10. Kinnard W. F., Choppin G. R. (1974) J. Inorg. Nucl. Chem.26: 1131

    Google Scholar 

  11. Lebiediew J. A., Jakowlew G. W. (1962) Radiochimija4: 304

    Google Scholar 

  12. Choppin G. R., Ketels J. (1965) J. Inorg. Nucl. Chem.27: 1335

    Google Scholar 

  13. Khopkar P. K., Mathur J. N. (1971) J. Inorg. Nucl. Chem.33: 495

    Google Scholar 

  14. Ceccaroli B. (1977) Doctoral Thesis. Strassburg (unpublished results)

  15. Coward N. A., Kiser R. W. (1966) J. Phys. Chem.70: 213

    Google Scholar 

  16. Hamze M., Meullemeestre J., Schwing M. J., Vierling F. (1986) J. Less Common Met.118: 153

    Google Scholar 

Download references

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Authors and Affiliations

  1. Faculty of Chemistry, Maria Curie Sklodowska University, PL-20-031, Lublin, Poland

    Pawel Sadowski & Marek Majdan

Authors
  1. Pawel Sadowski
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  2. Marek Majdan
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Sadowski, P., Majdan, M. Study of complexation in the Nd3+-SCN− system. Monatsh Chem 122, 241–245 (1991). https://doi.org/10.1007/BF00810823

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  • DOI: https://doi.org/10.1007/BF00810823

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