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Zur Kenntnis der wasserhaltigen schichtförmigen Alkali- und Erdalkali-Thiochromite der FormelM x (H2O) y CrS2

A contribution to the knowledge of the hydrated layered alkali and alkaline earth thiochromites of formulaM x(H2O) y CrS2

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Two different polytypic series (2s and 3s) of layered alkali and alkaline earth thiochromites of formulaM x(H2O) y CrS2 (x=0.2–0.4;y=0.18–0.5) were prepared by topotactic ion exchange in 2H- and 3R- K x (H2O) y CrS2. The products were studied by TGA and X-ray diffraction techniques. Hydrates with monomolecular (hydrates I) and bimolecular (hydrates II) water layers between the CrS2 slabs were observed. In the 3s series the CrS2 layers are stacked according to 3R (Ib) (hydrates I) and 3R (Ia) (hydrates II) structures. In the 2s series the layer stacking leads to a 2H (Ib) structure and to a new orthorhombic 2 O structure.

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität Wien, A-1090, Wien, Österreich

    Raimund Quint

  2. Institut für Chemie, Universität Linz, A-4040, Linz, Österreich

    Herbert Boller

  3. Institut für Anorganische Chemie, Universität Wien, A-1090, Wien, Österreich

    Herbert Blaha

Authors
  1. Raimund Quint
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  2. Herbert Boller
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  3. Herbert Blaha
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Additional information

Herrn Prof. Dr.K. Komarek zu seinem 60. Geburtstag gewidmet.

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Quint, R., Boller, H. & Blaha, H. Zur Kenntnis der wasserhaltigen schichtförmigen Alkali- und Erdalkali-Thiochromite der FormelM x (H2O) y CrS2 . Monatsh Chem 117, 1387–1397 (1986). https://doi.org/10.1007/BF00810748

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  • DOI: https://doi.org/10.1007/BF00810748

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