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Alkylester und N,N-Dimethylaminoethylester unsymmetrischer Phosphinsäuren

Alkylesters and N,N-dimethylaminoethylesters of unsymmetrical phosphinic acids

  • Organische Chemie Und Biochemie
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Summary

The phosphinic acid chlorides6 and9 react in good yields with N,N-dimethylaminoethanol to the corresponding esters3 and10. Reaction of the phenylphosphonous acid esters1 and2 with arylbromides, heteroarylbromides and carboxylic acid chlorides give esters of unsymmetrical phosphinic acids. Similarly, cyanphenylphosphinic acid ethylester reacts with aliphatic amines to phosphonic acid esterchlorides.

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Authors and Affiliations

  1. Pharmazeutisch-Chemisches Institut, Universität Heidelberg, D-6900, Heidelberg, Bundesrepublik Deutschland

    R. Neidlein & S. Buseck

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  1. R. Neidlein
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  2. S. Buseck
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Neidlein, R., Buseck, S. Alkylester und N,N-Dimethylaminoethylester unsymmetrischer Phosphinsäuren. Monatsh Chem 124, 309–317 (1993). https://doi.org/10.1007/BF00810588

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  • DOI: https://doi.org/10.1007/BF00810588

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