Skip to main content
Log in

Beiträge zur Chemie der Pyrrolpigmente, 69. Mitt.: Tripyrrine vom Prodigiosentyp als Ionophore

On the chemistry of pyrrole pigments, LXIX: Tripyrrines of the prodigiosene type as ionophores

  • Organische Chemie Und Biochemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

A compound of the prodigiosene type chromophore has been prepared and its carrier mediated transport properties for nearly all physiologically important cations determined using a bulk membrane system. This ligand is a very effective ionophore for these cations without pronounced selectivities. The mechanistic implications of complexation behaviour of the ligand for its transport characteristics are discussed: The physiological (bacteriostatic, fungistatic, antimitotic and toxic) properties of the prodigiosenes may be fundamentally correlated to their pronounced ionophoric properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literatur

  1. Mitt.:Eichinger D, Falk H (1987) Monatsh Chem 118: 91

    Google Scholar 

  2. Williams RP, Hearn WR (1967) Antibiotics II: 410

    Google Scholar 

  3. Gerber N (1975) Critical Rev Microbiol 1975: 469

    Google Scholar 

  4. Alonzo V (1984) L'Igiene Moderna 81: 557

    Google Scholar 

  5. Rapoport H, Castagnoli N (1962) J Amer Chem Soc 84: 2778

    Google Scholar 

  6. Rapoport H, Holden KG (1962) J Amer Chem Soc 84: 635

    Google Scholar 

  7. Hearn WR, Elson MK, Williams RH, Medina-Castro J (1970) J Org Chem 35: 142

    Google Scholar 

  8. Berner H, Schulz G, Reinshagen H (1977) Monatsh Chem 108: 233, 285, 915; (1978) 109: 137

    Google Scholar 

  9. Wir schlagen im Gegensatz zur Bezifferung des „Prodigiosins“ in Lit. [7] die in der Formelübersicht angegebene vor. Sie entspricht eher der Bezifferung von Tripyrrinen und Bilinen

  10. Fischer H (1941) Org Synth 21: 67

    Google Scholar 

  11. Plieninger H, Kurze J (1964) Ann Chem 680: 60

    Google Scholar 

  12. Silverstein RM, Ryskiewitz EE, Willard C, Köhler RC (1955) J Org Chem 20: 668

    Google Scholar 

  13. Eichinger D, Falk H (1982) Monatsh Chem 113: 355

    Google Scholar 

  14. Rosano H, Schulman JH, Weisbuch JB (1961) Ann NY Acad Sci 92: 457

    Google Scholar 

  15. Williams DR (1971) The metals of life. Van Nostrand Reinhold, London;Kiem J, Feinendegen LE (1985) Chem Lab Betr 36: 540

    Google Scholar 

  16. D'Ans-Lax (1967) Taschenbuch für Chemiker und Physiker, 3 Aufl. Springer, Berlin Heidelberg New York

    Google Scholar 

  17. Lamb JD, Christensen JJ, Oscarson JL, Nielsen BL, Asay BN, Izatt RM (1980) J Amer Chem Soc 102: 6820;Lehn JM, Behr JP, Kirch M (1985) J Amer Chem Soc 107: 241

    Google Scholar 

  18. Hilgenfeld R, Sänger W (1982) In: Host guest complex chemistry II. Top Curr Chem 101: 3

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Eichinger, D., Falk, H. Beiträge zur Chemie der Pyrrolpigmente, 69. Mitt.: Tripyrrine vom Prodigiosentyp als Ionophore. Monatsh Chem 118, 255–260 (1987). https://doi.org/10.1007/BF00810058

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00810058

Keywords

Navigation