Abstract
Crystals of Pb2(NO2)(NO3)(SeO3) were synthesized by partial reduction of nitrate ions with native copper under hydrothermal conditions. The crystal structure [a=5.529 (2) Å,b=10.357 (3) Å,c=6.811 (2) Å, space group Pmn21,Z=2] was determined from 1 707 independent X-ray data up to sin θ/λ=0.81 Å−1 and was refined toR w =0.028. The Pb(1) atom is ten coordinated to O atoms [Pb(1)-O from 2.51 Å to 2.96 Å], the Pb(2) atom has three nearest O atoms [Pb(2)-O=2.41 Å (1 ×) and 2.45 Å (2 ×)] and six next-nearest O atoms [Pb(2)-O from 2.80 Å to 3.22 Å].
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Herrn Prof. Dr.K. Komarek zum 60. Geburtstag gewidmet.
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Effenberger, H. Darstellung und Kristallstruktur von Pb2(NO2)(NO3)(SeO3). Monatsh Chem 118, 211–216 (1987). https://doi.org/10.1007/BF00810054
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DOI: https://doi.org/10.1007/BF00810054