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Enthalpies of mixing in the iron-manganese system by direct reaction calorimetry

Mischungsenthalpien im Eisen-Mangan-System mittels direkter Reaktionskalorimetrie

  • Anorganische Und Physikalische Chemie
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Abstract

Integral enthalpies of mixing of solid iron—manganese alloys have been obtained at 1443K, 1073K and 873K using a modified Dench-type calorimeter. The modifications in calorimetric technique required to cope with the high volatility of manganese are described. Results are presented and discussed.

Zusammenfassung

Mit Hilfe eines adiabatischen Kalorimeters des vonDench beschriebenen Typs wurden Mischungsenthalpien fester Eisen—Mangan-Legierungen bei 1443K, 1073K und 873K bestimmt. Die Modifikationen, die am Kalorimeter notwendig waren, um mit einem so flüchtigen Metall wie Mangan arbeiten zu können, sind beschrieben und die Ergebnisse diskutiert.

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Author notes

  1. Rainer Kubitz

    Present address: International Nickel Company Ltd., Birmingham, England

Authors and Affiliations

  1. Department of Metallurgy and Materials Science, University of Manchester/UMIST, M1 7HS, Manchester, England

    Rainer Kubitz & Frederick Henry Hayes

Authors
  1. Rainer Kubitz
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  2. Frederick Henry Hayes
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Additional information

Dedicated to Prof. Dr.Kurt L. Komarek on the occasion of his 60th birthday on 23rd June 1986.

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Kubitz, R., Hayes, F.H. Enthalpies of mixing in the iron-manganese system by direct reaction calorimetry. Monatsh Chem 118, 31–41 (1987). https://doi.org/10.1007/BF00810038

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  • DOI: https://doi.org/10.1007/BF00810038

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