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Reissert epoxides: Novel oxidation products of quinoline reissert compounds

Reissert-Epoxide: Neue Oxidationsprodukte von Chinolin-Reissert-Verbindungen (Kurze Mitt.)

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  • Organische Chemie Und Biochemie
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Summary

Treatment of quinoline Reissert compounds withm-chloroperoxybenzoic acid gave epoxides which are remarkably stable in crystalline state, but reactive in solution versus nucleophiles. They represent useful intermediates to regioselectively functionalized quinolines.

Zusammenfassung

Chinolin-Reissert-Verbindungen lassen sich mitm-Chlorperbenzoesäure zu Epoxiden oxidieren, die als kristalline Substanzen bemerkenswert stabil sind, in Lösung aber mit Nucleophilen bereitwillig reagieren. Sie stellen nützliche Zwischenprodukte zu regioselektiv funktionalisierten Chinolin-Derivaten dar.

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References

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Authors and Affiliations

  1. Institute of Pharmaceutical Chemistry, University of Vienna, A-1090, Wien, Austria

    Martin Kratzel & Romana Hiessböck

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  1. Martin Kratzel
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  2. Romana Hiessböck
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Kratzel, M., Hiessböck, R. Reissert epoxides: Novel oxidation products of quinoline reissert compounds. Monatsh Chem 124, 1207–1209 (1993). https://doi.org/10.1007/BF00810030

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  • DOI: https://doi.org/10.1007/BF00810030

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