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Zum Phänomen der induzierten optischen Aktivität: Der induzierte Circulardichroismus in Mischungsreihen

On the phenomenon of induced optical activity. The induced circular dichroism in mixtures

  • Organische Chemie Und Biochemie
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Abstract

The induced circular dichroism (ICD) of 4-Nitroso-N,N-dimethylaniline in a series of mixtures of CCl4, lactic and tartaric acid methylesters andcis-pinane, resp., was determined. From the dependence of the ICD on the concentration of chiral components the existence of a strong intermolecular interaction can be deduced—even in the case of apolarcis-pinane. Obviously the border line between associate induced CD (AICD) and dispersion induced CD (DICD) cannot be drawn unequivocally by experiment. The general phenomenology together with mechanistic models of ICD are discussed. It is proposed to use the term ICD exclusively, instead of others like AICD and DICD, which are only applicable when the predominant mechanism can be derived from experimental data. The term SICD (solvent induced CD) should be avoided for similar reasons.

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Authors and Affiliations

  1. Institut für Analytische, Organische und Physikalische Chemie, Johannes-Kepler-Universität, A-4040, Linz, Austria

    Heinz Falk, Walter Jungwirth & Norbert Müller

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  1. Heinz Falk
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  2. Walter Jungwirth
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  3. Norbert Müller
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Falk, H., Jungwirth, W. & Müller, N. Zum Phänomen der induzierten optischen Aktivität: Der induzierte Circulardichroismus in Mischungsreihen. Monatsh Chem 115, 455–466 (1984). https://doi.org/10.1007/BF00810007

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  • DOI: https://doi.org/10.1007/BF00810007

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