Skip to main content
SpringerLink
Log in

Kristallstruktur von Trisilber(I)amidosulfat-3-Ammoniak-2-Wasser, Ag3SO3N · 3NH3 · 2H2O

Crystal structure of trisilver(I) amidosulfate-3-ammonia-2-water, Ag3SO3N · 3NH3 · 2H2O

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

An X-ray crystal structure analysis of colourless Ag3SO3N · 3NH3 · 2H2O was carried out at room temperature:M=504.79, orthorhombic, P212121,a=6.275 (1) Å,b=11.826 (2) Å,c=14.299 (12) Å,V=1061.10 Å3,Z=4,d x=3.160 Mgm−3,F(000)=940, Mo Kα, λ=0.71069 Å (graphite monochromator), μ=5.60 mm−1,R=4.71%,R w=4.96% (982 reflections, 120 parameters). The structure consists of Ag ribbons; each Ag atom is linearly co-ordinated to two N atoms with distances corresponding to covalent Ag-N bonds; no Ag-O coordination is observed; the N atom of the SO3N group is surrounded by three Ag atoms; compared to amidosulfuric acid, the SO3N group shows significant deformation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Belaj F, Kratky Ch, Nachbaur E, Popitsch A (1987) Monatsh Chem 118: 19

    Google Scholar 

  2. Kemmer F (1985) Dissertation Univ Graz

  3. Kratky Ch, Nachbaur E, Popitsch A (1981) Monatsh Chem 112: 529

    Google Scholar 

  4. Belaj F,Kratky Ch,Nachbaur E,Popitsch A Monatsh Chem (im Druck)

  5. Chaumeton L (1936) Compt Rend Hebd Séances Acad Sci 202: 1783

    Google Scholar 

  6. Dostál K, Růžička A (1962) Z Chem 2: 88.

    Google Scholar 

  7. Dostál K, Růžička A (1965) Z Anorg Allg Chem 337: 325

    Google Scholar 

  8. Lecuir L (1941) Ann Chim (Paris) 15: 33

    Google Scholar 

  9. Paetzold R, Dostál K, Růžička A (1966) Z Anorg Allg Chem 348: 1

    Google Scholar 

  10. Masse R, Guitel JC, Durif A (1979) Acta Cryst B 35: 1428.

    Google Scholar 

  11. Masse R, Guitel JC, Durif A (1979) Acta Cryst B 35: 2823

    Google Scholar 

  12. Sheldrick GM (1976) SHELX76, a computer program for crystal structure determination. Univ of Cambridge, England

    Google Scholar 

  13. Germain G, Main P, Woolfson MM (1970) Acta Cryst B 26: 274.

    Google Scholar 

  14. Stewart JM (1976) The XRAY system. Tech Rep TR-446. Computer Science Center, Univ of Maryland, USA.

    Google Scholar 

  15. Motherwell S (1976) PLUTO, a program for plotting molecular and crystal structures. Cambridge Crystallographic Data Centre, England

    Google Scholar 

  16. Fawcett JK, Kocman V, Nyburg SC, O'Brien RJ (1969) J Chem Soc, Chem Commun 1969: 1198

    Google Scholar 

  17. Bats JW, Coppens P, Koetzle TF (1977) Acta Cryst B 33: 37

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität Graz, A-8010, Graz, Österreich

    Ferdinand Belaj & Christoph Kratky

  2. Derzeitige Adresse: Institut für Mineralogie und Kristallographie, Universität Wien, A-1010, Wien, Österreich

    Ferdinand Belaj

  3. Institut für Anorganische Chemie, Universität Graz, A-8010, Graz, Österreich

    Edgar Nachbaur & Alois Popitsch

Authors
  1. Ferdinand Belaj
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Christoph Kratky
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Edgar Nachbaur
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Alois Popitsch
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Belaj, F., Kratky, C., Nachbaur, E. et al. Kristallstruktur von Trisilber(I)amidosulfat-3-Ammoniak-2-Wasser, Ag3SO3N · 3NH3 · 2H2O. Monatsh Chem 118, 349–354 (1987). https://doi.org/10.1007/BF00809945

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00809945

Keywords

Search

Navigation