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Kristallstruktur und Konformation von 5-Carboxymethylaminomethyluridin Monohydrat

Crystal structure and conformation of 5-carboxymethylaminomethyluridine monohydrate

  • Organische Chemie Und Biochemie
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Summary

5-Carboxymethylaminomethyluridine crystallizes as a zwitterion in the monoclinic space group P21 witha=5.414 (2) Å,b=16.626 (2) Å,c=8.322 (1) Å, β=96.86 (a) Å,V=745.2 (3) Å3,Z=2,D=1.56 g/cm3. The structure was solved by direct methods and refined toR=0.061. The ribose ring assumes a C3′-endo-C2′-exo conformation and the torsion angle ϕCN is 9.6 (5)°. In the crystal, there are two intra- and ten intermolecular hydrogen bonds per asymmetrical unit.

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Authors and Affiliations

  1. Insitut für Allgemeine Chemie, Technische Universität, PL-90-924, Łódź, Polen

    Zdzisław Gałdecki

  2. Institut für Physik, Technische Universität, PL-90-924, Łódź, Polen

    Bernard Luciak

  3. Institut für Organische Chemie, Technische Universität, PL-90-924, Łódź, Polen

    Andrzej Małkiewicz & Barbara Nawrot

Authors
  1. Zdzisław Gałdecki
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  2. Bernard Luciak
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  3. Andrzej Małkiewicz
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  4. Barbara Nawrot
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Gałdecki, Z., Luciak, B., Małkiewicz, A. et al. Kristallstruktur und Konformation von 5-Carboxymethylaminomethyluridin Monohydrat. Monatsh Chem 122, 487–493 (1991). https://doi.org/10.1007/BF00809801

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  • DOI: https://doi.org/10.1007/BF00809801

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