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Monatshefte für Chemie / Chemical Monthly

, Volume 121, Issue 8–9, pp 703–707 | Cite as

Use of ethyl oxamate for syntheses of oxamato(-1) and novel μ-oxamato(-2) complexes

Short communication
  • Panayotis Th. Veltsistas
  • Spyros P. Perlepes
  • Miltiadis I. Karayannis
  • John M. Tsangaris
Organische Chemie Und Biochemie

Summary

The use of ethyl oxamate for the synthesis of inorganic oxamato complexes is reported. A reaction system leading to the preparation of the novel polymeric μ-oxamato(-2) complexes [M(oxm)(H2O)2] x (M=Cu, Zn, Cd), [Co(oxm)(H2O)2] x ·0.5xH2O and [Ni(oxm)(H2O)2] x ·xH2O is described (H2oxm = oxamic acid). Ethyl oxamate can also be used for the preparation of monomeric oxamato(-1) complexes.

Keywords

Ethyl oxamate Oxamato inorganic complexes μ-Oxamato bridges Magnetic moments 

Der Einsatz von Ethyloxamat für die Synthese von Oxamato(-1) und neuen μ-Oxamato(-2)-Komplexen (Kurze Mitt.)

Zusammenfassung

Es wird der Einsatz von Ethyloxamat für die Synthese von anorganischen Oxamato-Komplexen beschrieben. Ein Reaktions-System für die Herstellung von neuen μ-Oxamato(-2)-Komplexpolymeren: [M(oxm)(H2O)2] x ; (M = Cu, Zn, Cd), [Co(oxm)(H2O)2] x ·0.5xH2O und [Ni(oxm)(H2O)2] x ·xH2O, wird vorgestellt. Ethyloxamat kann auch für die Herstellung von monomeren Oxamato(-1)-Komplexen verwendet werden.

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Copyright information

© Springer-Verlag 1990

Authors and Affiliations

  • Panayotis Th. Veltsistas
    • 1
  • Spyros P. Perlepes
    • 1
  • Miltiadis I. Karayannis
    • 1
  • John M. Tsangaris
    • 1
  1. 1.Department of ChemistryUniversity of IoanninaIoanninaGreece

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