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Ein neues Oxoruthenat(IV): Ba4Ru1.1Mn1.9O10 mit statistischer Besetzung derM 4+-Metallpositionen

A new oxoruthenate(IV): Ba4Ru1.1Mn1.9O10 with statistically occupiedM 4+ positions

  • Anorganische Und Physikalische Chemie
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Summary

(I) Ba4Ru1.1Mn1.9O10 was prepared and investigated by single crystal X-ray technique. It crystallizes with orthorhombic symmetry, space group C 122v -Cmc2i,a=5.74;b=13.15;c=12.86 Å;Z=4. (I) showsM 3O12-groups of face connectedMO6-octahedra. The octahedra are occupied in different manner by Ru4+ and Mn4+. It belongs to compounds withM 3O12-octahedra-tripel connected in isolated two-dimensional wave-like planes.

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  1. Institut für Anorganische Chemie, Christian-Albrechts-Universität, D-2300, Kiel, Bundesrepublik Deutschland

    Marc Neubacher & Hanskarl Müller-Buschbaum

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  1. Marc Neubacher
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  2. Hanskarl Müller-Buschbaum
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Neubacher, M., Müller-Buschbaum, H. Ein neues Oxoruthenat(IV): Ba4Ru1.1Mn1.9O10 mit statistischer Besetzung derM 4+-Metallpositionen. Monatsh Chem 121, 635–640 (1990). https://doi.org/10.1007/BF00809766

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  • DOI: https://doi.org/10.1007/BF00809766

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