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Zum Schwingungsverhalten pentakoordinierter Zinn(IV)-organischer Verbindungen. IR- und Raman-Untersuchungen an 2,8,9-Tricarbastannatranen

The vibrational behaviour of pentaccordinated organo-tin(IV) compounds. IR and Raman investigations on 2,8,9-tricarbastannatranes

  • Anorganische Und Physikalische Chemie
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Summary

Results are reported of IR and Raman investigations on four 1-substituted 2,8,9-tricarbastannatranes (1,X=Cl;2,X=Br;3,X=I;4,X=Me). Group-theoretic investigations confirm the trigonal-bipyramidal configuration of the tin atoms. The vibrational frequencies of the coordination (Sn←N) are correlated to the distancesd (Sn-N). Besides the results on the vibrations of the coordination polyhedrons other results are reported concerning the enantiomerization of the chiral atran skeleton.

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Authors and Affiliations

  1. Martin-Luther-Universität Halle-Wittenberg, Sektion Chemie, DDR-4010, Halle (Saale), Deutsche Demokratische Republik

    Karla Schenzel & Alfred Kolbe

  2. Akademie der Wissenschaften der DDR, Zentralinstitut für PC, DDR-1199, Berlin-Adlershof, Deutsche Demokratische Republik

    Peter Reich

Authors
  1. Karla Schenzel
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  2. Alfred Kolbe
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  3. Peter Reich
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Schenzel, K., Kolbe, A. & Reich, P. Zum Schwingungsverhalten pentakoordinierter Zinn(IV)-organischer Verbindungen. IR- und Raman-Untersuchungen an 2,8,9-Tricarbastannatranen. Monatsh Chem 121, 615–623 (1990). https://doi.org/10.1007/BF00809764

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  • DOI: https://doi.org/10.1007/BF00809764

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