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Präparation und Kristallstrukturanalyse von Ca(N3)2(C5H5N)2

Preparation and structure analysis of Ca(N3)2(C5H5N)2

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Diazido-dipyridine-calcium was prepared by the reaction of Ca(N3)2 with pyridine. The crystals are tetragonal, space group I\(\bar 4\)2 m (121),N=2,a=699.7 (1),c=1 450.6 (5) pm. The crystal structure was determined by single crystal X-ray diffraction, 415 independent observed Mo-Kα-counter reflexions,R=0.049. The calcium atoms are sixcoordinated to four nitrogen atoms of azide groups and to two nitrogen atoms of pyridine. The coordination polyhedra are tetragonal bipyramids which are linked together by four azide groups to form sheets of composition Ca(N3)2. The pyridine rings are directed perpendicular to the sheets.

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Authors and Affiliations

  1. Abteilung für Strukturforschung, Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, A-8010, Graz, Österreich

    Franz Andreas Mautner & Harald Krischner

  2. Institut für Physikalische Chemie, Universität Graz, A-8010, Graz, Österreich

    Christoph Kratky

Authors
  1. Franz Andreas Mautner
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  2. Harald Krischner
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  3. Christoph Kratky
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Mautner, F.A., Krischner, H. & Kratky, C. Präparation und Kristallstrukturanalyse von Ca(N3)2(C5H5N)2 . Monatsh Chem 118, 567–572 (1987). https://doi.org/10.1007/BF00809666

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  • DOI: https://doi.org/10.1007/BF00809666

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