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Magnetic properties of group VIB hexacarbonyls. Suggestion of a new diamagnetic susceptibility standard

Magnetische Eigenschaften von Hexacarbonylen der Gruppe VI B. Vorschlag zu einem neuen diamagnetischen Suszeptibilitätsstandard

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  • Anorganische Und Physikalische Chemie
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Summary

Careful measurements of the magnetic susceptibilities of group VI B metal hexacarbonyls show an ideal diamagnetic behaviour. The properties of W(CO)6, together with the relatively low price, lead to the suggestion of W(CO)6 as a new calibration standard for the diamagnetic region.

Zusammenfassung

Sorgfältige Messungen der magnetischen Suszeptibilität der Metallhexacarbonyle der Gruppe VI B zeigen deren ideal diamagnetisches Verhalten. Die physikalischen Eigenschaften des W(CO)6, zusammen mit dem relativ niedrigen Preis, prädestinieren es als diamagnetischen Eichstandard.

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Authors and Affiliations

  1. Institute of Physical and Theoretical Chemistry, University of Technology, A-8010, Graz, Austria

    Gunter Sperka & Harald P. Fritzer

Authors
  1. Gunter Sperka
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  2. Harald P. Fritzer
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Sperka, G., Fritzer, H.P. Magnetic properties of group VIB hexacarbonyls. Suggestion of a new diamagnetic susceptibility standard. Monatsh Chem 120, 25–26 (1989). https://doi.org/10.1007/BF00809645

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  • DOI: https://doi.org/10.1007/BF00809645

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