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Fluordiazadiphosphetidine, 20. Mitt. Die Dehydrofluorierung zwitterionischer und die Hydrofluorierung neutraler, hydrazinsubstituierter Fluordiazadiphosphetidine

Fluorodiazadiphosphetidines, XX: The dehydrofluorination of betainic, and the hydrofluorination of covalent hydrazinosubstituted fluorodiazadiphosphetidines

  • Anorganische Und Physikalische Chemie
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Abstract

In the presence ofEt 3N·PF5, F4P−(CH3N)2PF2NHNH+(CH3)2 (I) looses one molecule of HF to yield F3P(CH3N)2PF2NHN(CH3)2 (II). The reaction ofI withDABCO (1,4-diazabicyclo[2.2.2]octane) yieldsDABCO·2H++(CH3NPF4) −−2 (III) and [CH3NPF2NHN(CH3)2]2 (IV). Even in the presence of CsF,II does not react with HF.

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Literatur

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Technische Universität, A-1060, Wien, Österreich

    Klaus Galle & Kurt Utvary

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  1. Klaus Galle
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  2. Kurt Utvary
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Galle, K., Utvary, K. Fluordiazadiphosphetidine, 20. Mitt. Die Dehydrofluorierung zwitterionischer und die Hydrofluorierung neutraler, hydrazinsubstituierter Fluordiazadiphosphetidine. Monatsh Chem 119, 173–176 (1988). https://doi.org/10.1007/BF00809591

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  • DOI: https://doi.org/10.1007/BF00809591

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