Skip to main content
SpringerLink
Log in

Vibronisches Spektralverhalten von Molekülen, 16. Mitt.: Theoretische Molekülgeometrien und Spektrumstruktur der Fluoreszenz des Anthanthrens

Vibronic spectral behaviour of molecules: Theoretical molecular geometries and spectrum structure of the fluorescence of anthanthrene (short communication)

Kurze Mitteilung

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

Completely-optimized S0 and S1 molecular geometries of anthanthrene and the theoretical vibronic line spectrum of the S1 → S0 fluorescence are presented. The experimental spectroscopic peaks are satisfactorily reproduced by the calculated vibronic transitions within the Condon approach. An analysis of the active vibrational modes being responsible for the spectrum structure is given. The photophysical S1 state deactivation of anthanthrene is discussed with respect to the fluorescence and internal conversion quantum yields.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literatur

  1. 15. Mitt.: Gustav K., Storch M. (im Druck) J. prakt. Chem.

  2. Berlman I. B. (1971) Handbook of Fluorescence Spectra of Aromatic Molecules. Academic Press, New York London

    Google Scholar 

  3. Thomaz M. F., Barradas M. I., Stevens B. (1972) Chem. Phys. Lett.17: 160

    Google Scholar 

  4. Stevens B., Algar B. E. (1969) J. Phys. Chem.73: 1711

    Google Scholar 

  5. Warshel A., Dauber P. (1977) J. Chem. Phys.66: 5477; Storch M. (1988) QCFFVC-PI-Programmdokumentation. Sektion Chemie der Friedrich-Schiller-Universität Jena

    Google Scholar 

  6. Warshel A., Karplus M. (1972) J. Am. Chem. Soc.94: 5612

    Google Scholar 

  7. Condon E. U. (1928) Phys. Rev.32: 858; Roche M., Jaffé H. H. (1976) Chem. Soc. Rev.5: 165

    Google Scholar 

  8. Jung Ch. (1979) FRACON-Programmdokumentation Quantenchemie. Akademie der Wissenschaften der DDR, Berlin; Storch M. (1988) FCHT-Programmdokumentation Photophysikalische Chemie. Sektion Chemie der Friedrich-Schiller-Universität Jena

    Google Scholar 

  9. Gustav K., Storch M. (in Vorbereitung)

  10. Gustav K., Seydenschwanz C. (1984) Chem. Phys. Lett.109: 156; Gustav K., Storch M. (1986) Monatsh. Chem.117: 1007

    Google Scholar 

  11. Gustav K., Storch M., Jung Ch. (1989) Acta Phys. Polon.A 76: 883

    Google Scholar 

  12. Dushinsky F. (1937) Acta Physicochim. URSS7: 551

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Sektion Chemie, Friedrich-Schiller-Universität Jena, DDR-6900, Jena, Deutsche Demokratische Republik

    Klaus Gustav & Michael Storch

Authors
  1. Klaus Gustav
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Michael Storch
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gustav, K., Storch, M. Vibronisches Spektralverhalten von Molekülen, 16. Mitt.: Theoretische Molekülgeometrien und Spektrumstruktur der Fluoreszenz des Anthanthrens. Monatsh Chem 121, 141–145 (1990). https://doi.org/10.1007/BF00809526

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00809526

Keywords

Search

Navigation