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Kristallstruktur und thermisches Verhalten der Additionsverbindungen von Trithiocyanursäure mit Tetrahydrofuran und 1,4-Dioxan

Crystal structure and thermical behaviour of addition-compounds of trithiocyanuric acid with tetrahydrofuran and 1,4-dioxane

  • Anorganische Und Physikalische Chemie
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Summary

The addition compounds trithiocyanuric acid-tetrahydrofuran (1), 2-trithiocyanuric acid-3-(1,4-dioxane) (2) and 2-trithiocyanuric acid-(1,4-dioxane) (3) were prepared and their thermogravimetric behaviour studied. X-ray crystal structure analyses of1 and2 were carried out at 100 K.1: (HNCS)3·C4H8O,M r=249.37, monoclinic, P 22/c,a=11.105 (1),b=12.715 (1),c=7.825 (1) Å, β=83.32 (1)°,V=1097.4(1) Å3,Z=4,d x=1.509 g/cm3,R=3.65%,R w=3.53% (1 929 observables, 147 parameters).2: 2 (HNCS)3·3C4H8O2,M r=618.83, triclinic,\(P\bar 1\),a=4.339(1),b=12.471(1),c=13.265(1) Å, α=73.08(1)°, β=84.29(1)°, γ=80.73(1)°,V=677.1(2) Å3,Z=1,d x=1.518 g/cm3,R=4.20%,R w=3.75% (2 521 observables, 223 parameters). Finally, the solubilities of cyanuric acid (4) and of trithiocyanuric acid (5) in water, methanol, tetrahydrofuran and 1,4-dioxane at 25°C were determined.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Universität Graz, A-8010, Graz, Österreich

    Ferdinand Belaj, Robert Tripolt & Edgar Nachbaur

Authors
  1. Ferdinand Belaj
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  2. Robert Tripolt
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  3. Edgar Nachbaur
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Belaj, F., Tripolt, R. & Nachbaur, E. Kristallstruktur und thermisches Verhalten der Additionsverbindungen von Trithiocyanursäure mit Tetrahydrofuran und 1,4-Dioxan. Monatsh Chem 121, 99–108 (1990). https://doi.org/10.1007/BF00809521

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  • DOI: https://doi.org/10.1007/BF00809521

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