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Coordinating ability of the heterocycles 1,3-dithia-2-arsa and stiba-cyclopentanes toward sulfur containing ligands, part I. Dialkyl-dithiocarbamate complexes

Die Koordinationsfähigkeit der Heterocyclen 1,3-Dithia-2-arsa- und-stiba-cyclopentan gegenüber Schwefel enthaltenden Liganden, I. Dialkyldithiocarbamat-Komplexe

  • Organische Chemie Und Biochemie
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Summary

The heterocyclic compounds ClMS2 (CH2)2 (M = As, Sb) are tested by first time as source of starting materials in the synthesis of complexes. The preparation and characterization of heterocyclic dithiocarbamatesR 2NCS2 MS2 (CH2)2, (M = As, Sb;R =Me,Et,i-Pr) is reported. Spectroscopic and analytical data suggest a bidentate behavior of the dithiocarbamate entity and the presence of aMS4 core.

Zusammenfassung

Die heterocyclischen Verbindungen ClMS2 (CH2)2 (M = As, Sb) werden erstmals als Quelle für Ausgangsmaterial zur Synthese von Komplexen herangezogen. Es wird über die Herstellung und Charakterisierung der heterocyclischen DithiocarbamateR 2NCS2 MS2 (CH2)2 (M = As, Sb;R =Me,Et,i-Pr) berichtet. Spektroskopische und analytische Daten sprechen für ein bidentates Verhalten der Dithiocarbamat-Einheit und der Präsenz einerMS4-Anordnung im Komplex.

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Authors and Affiliations

  1. Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, 04510, México, D.F. Mexico

    Raymundo Cea-Olivares, Jesús Wingartz, Elsa Ríos & Jesús Valdés-Martinez

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  1. Raymundo Cea-Olivares
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  2. Jesús Wingartz
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  3. Elsa Ríos
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  4. Jesús Valdés-Martinez
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Cea-Olivares, R., Wingartz, J., Ríos, E. et al. Coordinating ability of the heterocycles 1,3-dithia-2-arsa and stiba-cyclopentanes toward sulfur containing ligands, part I. Dialkyl-dithiocarbamate complexes. Monatsh Chem 121, 377–383 (1990). https://doi.org/10.1007/BF00809454

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  • DOI: https://doi.org/10.1007/BF00809454

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