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Pheromone, 2. Mitt. Ein Verfahren zur Herstellung von Ketonen und Spiroketalen durch Entschwefelung von Thienylethern

A method for the synthesis of ketones and spiroketals via desulfurization of thienylethers

  • Organische Chemie Und Biochemie
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Summary

Starting from substituted methoxythiophenes1 ketones and spiroketals can be synthesized in one step by desulfurization with partial hydrogenation. The bark beetle pheromone chalcogran2 a and the wasp anti aggression pheromone2 b were prepared by this method.

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Authors and Affiliations

  1. Christian-Doppler-Laboratorium für Chirale Verbindungen: Chemische Synthese, Getreidemarkt 9, A-1060, Wien, Österreich

    Christian R. Noe & Peter Gärtner

  2. Institut für Organische Chemie, Technische Universität Wien, Getreidemarkt 9, A-1060, Wien, Österreich

    Max Knollmüller & Karin Dungler

Authors
  1. Christian R. Noe
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  2. Max Knollmüller
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  3. Karin Dungler
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  4. Peter Gärtner
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Prof. Dr. F. Sauter zum 60. Geburtstag gewidmet

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Noe, C.R., Knollmüller, M., Dungler, K. et al. Pheromone, 2. Mitt. Ein Verfahren zur Herstellung von Ketonen und Spiroketalen durch Entschwefelung von Thienylethern. Monatsh Chem 122, 185–194 (1991). https://doi.org/10.1007/BF00809364

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  • DOI: https://doi.org/10.1007/BF00809364

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