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A study of polyamine complex formation with H+, Cu(II), Zn(II), Pb(II), and Mg(II) in aqueous solution

Untersuchungen zur Komplexbildung von Polyaminen mit H+, Cu(II), Zn(II), Pb(II) und Mg(II) in wäßriger Lösung

  • Anorganische Und Physikalische Chemie
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Summary

The composition and stability of the following biogenic amine complexes have been investigated: 1,4-diaminobutane(Put), 4-azaoctane-1,8-diamine(Spd), 4,9-diazadodecan-1, 12-diamine(Spm) as well as homologues such as 1,3-diaminopropane(Put3), 4-azaheptane-1, 7-diamine(Spd3,3) and 4,8-diazaundecan-1,11-diamine(Spm3,3,3) with H+, Cu(II), Zn(II), Pb(II) and Mg(II). A potentiometric method was used. The VIS technique enabled the determination of coordination mode in copper/amine systems. It was found that Mg(II) does not form coordination compounds with any of the studied polyamines in solution. An increase in the concentration of ligand and metal was found to result in a stronger tendency towards the formation of protonated compounds accompanied by a decrease in the concentration of hydroxocomplexes. At physiologicalpH (7.4) an increase in the concentration of protonated compounds by approximately 15% was observed within the ligand concentration range from 0.001 mol dm−3 to 0.0001 mol dm−3 at a Cu(II) concentration of 0.000177 mol dm−3.

Zusammenfassung

Anhand einer Analyse von potentiometrischen Daten wurden Zusammensetzung und Beständigkeit folgender biogener Aminkomplexe untersucht: 1,4-Diaminobutan(Put), 4-Azaoktan-1,8-diamin(Spd), 4,9-Diazadodekan-1,12-diamin(Spm), sowie auch deren Homologen 1,3-Diaminopropan(Put3), 4-Azaheptan-1,7-diamin(Spd3,3) und 4,8-Diazaundekan-1,11-diamin(Spm3,3,3) mit H+, Cu(II), Zn(II), Pb(II) und Mg(II). Mit Hilfe der VIS-Technik wurde die Koordinationsweise in Kupfer/Amin-Systemen bestimmt. Es wurde festgestellt, daß Mg(II) keine Koordinationsverbindungen mit den untersuchten Polyaminen bildet. Eine höhere Konzentration von Ligand und Metall führte zu stärkerer Tendenz der Bildung protonierter Verbindungen, wobei die Konzentration von Hydroxokomplexen kleiner wurde. Bei physiologischempH (7.4) wurde im Bereich der Ligand-Konzentration von 0.001 mol dm−3 bis 0.0001 mol dm−3 bei einer Cu(II)-Konzentration von 0.000177 mol dm−3 ein Anstieg der Konzentration protonierter Verbindungen um etwa 15% beobachtet.

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Authors and Affiliations

  1. Faculty of Chemistry, Adam Mickiewicz University, PL-60-780, Poznań, Poland

    Anna Wojciechowska, Leszek Bolewski & Lechoslaw Lomozik

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  1. Anna Wojciechowska
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  2. Leszek Bolewski
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  3. Lechoslaw Lomozik
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Wojciechowska, A., Bolewski, L. & Lomozik, L. A study of polyamine complex formation with H+, Cu(II), Zn(II), Pb(II), and Mg(II) in aqueous solution. Monatsh Chem 122, 131–138 (1991). https://doi.org/10.1007/BF00809357

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  • DOI: https://doi.org/10.1007/BF00809357

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