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Über die Bildung eines neuen, stark fluoreszierenden Heterocyclus bei der versuchten Quarterinisierung von Chinolin

On the formation of a new, highly fluorescent heterocyclic system during an attempted quarternization of quinoline

  • Organische Chemie Und Biochemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

When quinoline is treated with ethyl bromoacetate in ethanol at a molar ratio of 1.5:1, a highly fluorescent pyrrolodiquinolinium ion (2a) is formed along with quarternized quinoline (1a). The structure of2a has been established by infrared, proton magnetic resonance and mass spectroscopy as well as by its characteristic ultraviolet absorption spectrum.

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Literatur

  1. Rhoussopoulos O., Ber. dtsch. chem. Ges.15, 2006 (1882).

    Google Scholar 

  2. Ihlder R., Archiv Pharmaz.240, 517 (1902).

    Google Scholar 

  3. Wedekind E., Oechslen R., Ber. dtsch. chem. Ges.35, 3586 (1902).

    Google Scholar 

  4. Hantzsch A., Kalb M., Ber. dtsch. chem. Ges.32, 3109 (1899).

    Google Scholar 

  5. Aston J. G., Lasselle P. A., J. Amer. Chem. Soc.56, 426 (1934).

    Google Scholar 

  6. von Braun J., Ber. dtsch. chem. Ges.33, 1438 (1900).

    Google Scholar 

  7. Shimidzu T., J. Pharm. Soc. Japan529, 243 (1926).

    Google Scholar 

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Authors and Affiliations

  1. Institut für Organische Chemie, Karl-Franzens-Universität Graz, A-8010, Graz, Österreich

    Erich Ziegler, Helga Wittmann, Otto S. Wolfbeis & Heinz Sterk

Authors
  1. Erich Ziegler
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  2. Helga Wittmann
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  3. Otto S. Wolfbeis
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  4. Heinz Sterk
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Additional information

Herrn Prof. Dr.K. Schlögl, Universität Wien, zur Vollendung des 60. Lebensjahres mit besten Wünschen gewidmet.

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Ziegler, E., Wittmann, H., Wolfbeis, O.S. et al. Über die Bildung eines neuen, stark fluoreszierenden Heterocyclus bei der versuchten Quarterinisierung von Chinolin. Monatsh Chem 115, 1165–1170 (1984). https://doi.org/10.1007/BF00809348

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  • DOI: https://doi.org/10.1007/BF00809348

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