Skip to main content
SpringerLink
Log in

Tl2SnS3 — ein Thiostannat mit ∞1 -[SnS 2−3 ]-Ketten

Tl2SnS3 — A thiostannate with ∞1 -[SnS 2−3 ]-chains

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Black, fibre-like crystals of Tl2SnS3 were obtained from the melt using high-purity elements. Tl2SnS3 is monoclinic, space group C 2/m witha=23.03 (1),b=3.834 (1),c=7.379 (3) Å, β=94.07 (5)°;Z=4. The crystal structure was determined from single crystal diffractometer intensity data and refined to a conventionalR of 0.127 for 724 observed reflections. The crystal structure is of a new type. It is characterized by infinite chains, ∞1 -[SnS 2−3 ], formed by cornersharing SnS4-tetrahedra. These chains run along [010], their translation period comprises one tetrahedron (“Einerketten”). The average Sn — S-distance is 2.397 Å. The Tl+-ions separating the thiostannate-chains have different sulfur coordination. The coordination figure of Tl(1) is a bicapped trigonal prism, Tl(2) is in the center of an irregular cube. A comparison of the thiostannate-chains with other simple chains built-up by corner-sharing tetrahedra is given.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Krebs B., Angew. Chem.95, 113 (1983).

    Google Scholar 

  2. Jumas J. C., Vermot-Gaud-Daniel F., Philippot E., Cryst. Struct. Comm.2, 157 (1973).

    Google Scholar 

  3. Jumas J. C., Philippot E., Vermot-Gaud-Daniel F., Ribes M., Maurin M., J. Solid State Chem.14, 319 (1975).

    Google Scholar 

  4. Krebs B., Schiwy W., Z. anorg. allg. Chem.398, 63 (1973).

    Google Scholar 

  5. Mark W., Lindqvist O., Jumas J. C., Philippot E., Acta Cryst.B 30, 2620 (1974).

    Google Scholar 

  6. Krebs B., Pohl S., Schiwy W., Z. anorg. allg. Chem.393, 241 (1972).

    Google Scholar 

  7. Jumas J. C., Philippot E., Maurin M., J. Solid State Chem.14, 152 (1972).

    Google Scholar 

  8. Klepp K. O., Eulenberger G., Z. Naturforsch.39 b, 705 (1984).

    Google Scholar 

  9. Eulenberger G., Z. Naturforsch.36 b, 687 (1981).

    Google Scholar 

  10. The X-RAY-System (1976). Techn. Rep. TR-446, Computer Science Center, Univ. of Maryland, College Park, Maryland, U.S.A.

  11. Cromer D. T., Mann J. B., Acta Cryst.A 24, 321 (1968).

    Google Scholar 

  12. International Tables for X-Ray Crystallography, Vol. IV. Birmingham: The Kynoch Press. 1974.

  13. Liebau F., Naturwiss.49, 41 (1962).

    Google Scholar 

  14. Schiwy W., Blutau Cl., Gäthje D., Krebs B., Z. anorg. allg. Chem.412, 1 (1975).

    Google Scholar 

  15. Shannon R. D., In: Structure and Bonding in Crystals (Navrotsky A., O'Keefe M., Hrsg.), Vol. II, S. 53. New York: Academic Press. 1981.

    Google Scholar 

  16. Brink C., MacGillavry C. H., Acta Cryst.2, 158 (1949).

    Google Scholar 

  17. Brink C., Stenfert-Kroese H. A., Acta Cryst.5, 433 (1952).

    Google Scholar 

  18. Brink C., vanArkel A. E., Acta Cryst.5, 506 (1952).

    Google Scholar 

  19. Pauling L., In: The Nature of the Chemical Bond. Ithaca: Cornell Univ. Press. 1940.

    Google Scholar 

  20. Ribes M., Olivier-Fourcade J., Philippot E., Maurin M., Rev. Chim. Min%er.9, 757 (1972).

    Google Scholar 

  21. Schartau W., Hoppe R., Z. anorg. allg. Chem.408, 60 (1974).

    Google Scholar 

  22. Völlenkle H., Z. Krist.154, 77 (1981).

    Google Scholar 

  23. McDonald W. S., Cruickshank D. W. J., Acta Cryst.22, 37 (1967).

    Google Scholar 

  24. Cruickshank D. W. J., Kálman A., Stephens J. S., Acta Cryst.B 34, 1333 (1978).

    Google Scholar 

  25. Grey I. E., Steinfink H., Inorg. Chem.10, 691 (1971).

    Google Scholar 

  26. Iglesias J. E., Pachali K. E., Steinfink H., J. Solid State Chem.9, 6 (1974).

    Google Scholar 

  27. Sommer H., Hoppe R., Z. anorg. allg. Chem.443, 201 (1978).

    Google Scholar 

  28. Hong H. Y., Steinfink H., J. Solid State Chem.5, 93 (1972).

    Google Scholar 

  29. v. Schnering H. G., Hoppe R., Z. anorg. allg. Chem.312, 99 (1961).

    Google Scholar 

  30. Jaulmes S., Houenou P., Mat. Res. Bull.15, 911 (1980).

    Google Scholar 

  31. Ajavon A.-L., Eholie R., Piffard Y., Tournoux M., Rev. Chim. Minér.20, 421 (1983).

    Google Scholar 

  32. Yvon K., Jeitschko W., Parthé E., J. Appl. Cryst.10, 73 (1977).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Anorganische Chemie, Rheinisch-Westfälisch Technische Hochschule, Aachen, D-5100, Aachen, Bundesrepublik Deutschland

    Kurt O. Klepp

Authors
  1. Kurt O. Klepp
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Herrn Prof. Dr.Karl Schlögl zum 60. Geburtstag gewidmet.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Klepp, K.O. Tl2SnS3 — ein Thiostannat mit ∞1 -[SnS 2−3 ]-Ketten. Monatsh Chem 115, 1133–1142 (1984). https://doi.org/10.1007/BF00809344

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00809344

Keywords

Search

Navigation