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Die Kristallstruktur eines polynuklearen Co(II)-Komplexes in Cs2[Co3(N3)8]

The crystal structure of a polynuclear Co(II)-complex in Cs2[Co3(N3)8]

  • Anorganische Und Physikalische Chemie
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Abstract

Cs2[Co3(N3)8] crystallizes monoclinic,a=1 123.8 (3),b=568.4 (2),c=1 542.6 (4) pm, β=107.37 (2)°, space group P21/n,Z=2. The crystal structure was determined by single crystal X-ray diffraction,R w=0.069. Coatoms are coordinated octahedrally to six azide groups and form polynuclear complexes of composition [Co3(N3)8]2−. The complex anions share edges and are connected to infinite chains running along theb-axis direction. Cesium is irregularly surrounded by azide groups.

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Authors and Affiliations

  1. Institut für Physikalische und Theoretische Chemie, Abteilung für Strukturforschung, Technische Universität Graz, A-8010, Graz, Österreich

    Franz A. Mautner & Harald Krischner

  2. Institut für Physikalische Chemie, Universität Graz, A-8010, Graz, Österreich

    Christoph Kratky

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  1. Franz A. Mautner
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  2. Harald Krischner
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  3. Christoph Kratky
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Mautner, F.A., Krischner, H. & Kratky, C. Die Kristallstruktur eines polynuklearen Co(II)-Komplexes in Cs2[Co3(N3)8]. Monatsh Chem 119, 509–514 (1988). https://doi.org/10.1007/BF00809202

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  • DOI: https://doi.org/10.1007/BF00809202

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