Monatshefte für Chemie / Chemical Monthly

, Volume 116, Issue 8–9, pp 1103–1105 | Cite as

The reaction of alkoxides with dicobalt octacarbonyl: Trapping of the Co(I) intermediate in the disproportionation (“base reaction”) with a hardLewis base

Short communication
  • Miklós Tasi
  • Attila Sisak
  • Ferenc Ungváry
  • Gyula Pályi
Organische Chemie And Biochemie


Dicobalt octacarbonyl reacts with alcoholates (RO) yielding alkoxycarbonylcobalt tetracarbonyls,ROC(O)Co(CO)4.


Alkoxides, reaction with dicobalt octacarbonyl Alkoxycarbonylcobalt tetracarbonyls Hydrocarbalkoxylation intermediates 

Reaktion von Alkoxiden mit Dicobaltoctacarbonyl: Abfangen des Co(I) Zwischenproduktes in der Disproportionierung („Basen-Reaktion“) mit einer hartenLewis Base (Kurze Mitteilung)


Dicobaltoctacarbonyl reagiert mit Alkoxiden (RO) zu Alkoxycarbonylcobalt tetracarbonylen,ROC(O)Co(CO)4.


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Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • Miklós Tasi
    • 1
  • Attila Sisak
    • 2
  • Ferenc Ungváry
    • 1
  • Gyula Pályi
    • 2
  1. 1.Institute of Organic ChemistryUniversity of VeszprémVeszprémHungary
  2. 2.Research Group for PetrochemistryHungarian Academy of SciencesVeszprémHungary

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