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Monatshefte für Chemie / Chemical Monthly

, Volume 116, Issue 8–9, pp 1103–1105 | Cite as

The reaction of alkoxides with dicobalt octacarbonyl: Trapping of the Co(I) intermediate in the disproportionation (“base reaction”) with a hardLewis base

Short communication
  • Miklós Tasi
  • Attila Sisak
  • Ferenc Ungváry
  • Gyula Pályi
Organische Chemie And Biochemie

Abstract

Dicobalt octacarbonyl reacts with alcoholates (RO) yielding alkoxycarbonylcobalt tetracarbonyls,ROC(O)Co(CO)4.

Keywords

Alkoxides, reaction with dicobalt octacarbonyl Alkoxycarbonylcobalt tetracarbonyls Hydrocarbalkoxylation intermediates 

Reaktion von Alkoxiden mit Dicobaltoctacarbonyl: Abfangen des Co(I) Zwischenproduktes in der Disproportionierung („Basen-Reaktion“) mit einer hartenLewis Base (Kurze Mitteilung)

Zusammenfassung

Dicobaltoctacarbonyl reagiert mit Alkoxiden (RO) zu Alkoxycarbonylcobalt tetracarbonylen,ROC(O)Co(CO)4.

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Copyright information

© Springer-Verlag 1985

Authors and Affiliations

  • Miklós Tasi
    • 1
  • Attila Sisak
    • 2
  • Ferenc Ungváry
    • 1
  • Gyula Pályi
    • 2
  1. 1.Institute of Organic ChemistryUniversity of VeszprémVeszprémHungary
  2. 2.Research Group for PetrochemistryHungarian Academy of SciencesVeszprémHungary

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