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Ortho-Formylierung von Anilinen durch Umlagerung von Bis(methylthio)methan-S-(N-aryl)imiden

Ortho-formylation of anilines by rearrangement of bis(methylthio)methane-S-(N-aryl)imides

  • Organische Chemie And Biochemie
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Abstract

By reaction of anilines with dithioacetals of formaldehyde [in particular, with bis(methylthio)methane] andtert. butylhypochlorite the corresponding intermediate mono-sulfimides are formed which rearrange easily—after addition of triethylamine—to yield dithioacetals5 ofo-amino benzaldehydes.

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Authors and Affiliations

  1. Institut für Organische Chemie, Universität Wien, A-1090, Wien, Österreich

    Peter K. Claus, Emmerich Jäger & Alexis Setzer

Authors
  1. Peter K. Claus
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  2. Emmerich Jäger
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  3. Alexis Setzer
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Herrn emer. o. Univ. Prof. Dr.O. Hromatka zum 80. Geburtstag gewidmet.

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Claus, P.K., Jäger, E. & Setzer, A. Ortho-Formylierung von Anilinen durch Umlagerung von Bis(methylthio)methan-S-(N-aryl)imiden. Monatsh Chem 116, 1017–1026 (1985). https://doi.org/10.1007/BF00809194

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  • DOI: https://doi.org/10.1007/BF00809194

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