Abstract
Using total evaporation of crude oil fractions in the direct inlet the molecular weight distribution and the overall range of cycle numbers presented (“Zyklenanalyse”) via computer averaged integrating field ionisation mass spectrometry (FI-CAI) have been investigated. The correlation of the results with the data obtained from the standard EI-MS inverted matrix method revealed the maximal single deviation of 3.3%. The crude oil probes (0.1mg) contained saturated hydrocarbons in the range of 17 to 36 C-atoms. Limits, usability and the specific information of this method are discussed.
Similar content being viewed by others
Literatur
Hinds G. P., Proc. API, Div. Refining49, 147 (1969).
Hinds G. P., Proc. API, Div. Refining50, 279 (1970).
Hinds G. P., Proc. API, Div. Refining52, 691 (1972).
Severin D.,Benninghoff U., Forschungsbericht DGMK-197, kurze Zusammenf. s. EKEP Synopse 8048 Erdöl und Gas (1981).
Mead W. L., Anal. Chem.40, 743 (1968).
Hirsch D. E.,Dooley J. E.,Coleman H. J.,Thompson C. J., U.S. Bureau of Mines, Report 7893.
Delpuech J. J., Plenary Lectures, GERM VI, Pont a Mousson, March 10–12, 1982.
Hood A.,O'Neal M. J., Advances in Mass Spectrometry AMSPA, Waldron, 175 (1959).
ANSI/ASTM D 2786-71 (Reapproved 1976) Standard Method for Hydrocarbon Types Analysis of Gas-Oil Saturates Fractions by High Ionising Voltage Mass Spectrometry.
Ruth J. M., Anal. Chem.40, 747 (1968).
Kuras M., Ryska M., Mostecky J., Anal. Chem.48, 196 (1976).
Scheppele S. E., Int. J. Mass Spectrom. Ion Phys.28, 35 (1978).
Nikiforov A., Comp. enh. Spectroscopy, in Vorbereitung.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Koci, K., Nikiforov, A. Zyklenanalyse petrochemischer Systeme mittels rechnergemittelter akkumulierender Feldionisation-Massenspektrometrie (FI-CAI). Monatsh Chem 113, 1459–1467 (1982). https://doi.org/10.1007/BF00808945
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00808945