Abstract
The kinetics of the iron(II) reduction of thallium(III) oxinate does not differ essentially from that of the oxinate-transfer from thallium(III)-oxinate to iron(III), described before: formation of a binuclear intermediate, rearrangements within, and subsequent reaction with the excess reactant to the final products. As for the redox process, these intermediates are binuclear Tl(II)-Fe(III) complexes which, with initial reactants, form further complexes in which the second electron is transferred. In the cases of excess Tl(ox)3 and of equimolar reactants, disproportionations are likely involved.
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Literatur
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Soukup, R.W., Sapunov, V.N., Ateshykashi, H. et al. Redoxkinetik von Metallkomplexen in nichtwäßrigen Lösungen, XI. Die Reduktion von Thallium(III)oxinat mit Eisen(II) in schwach koordinierenden Lösungsmitteln. Monatsh Chem 113, 1349–1366 (1982). https://doi.org/10.1007/BF00808936
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DOI: https://doi.org/10.1007/BF00808936