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Preparation and examination of properties of lanthanide chloride salts with hexamethylenetetramine

Darstellung und Untersuchung der Eigenschaften von Komplexsalzen der Lanthanidchloride mit Hexamethylentetramin

  • Anorganische Und Physikalische Chemie
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Summary

New complex salts of lanthanide chlorides with hexamethylenetramine of the general formulaLnCl3·2HMTA·nH2O [Ln=La, Pr, Nd, Sm, Dy, Er;HMTA-hexamethylenetetramine N4(CH2)6;n=8, 10, 12] have been obtained. On the basis of IR IR spectra (4000-200cm−1) and Raman spectra (3000-300 cm−1), changes in the coordination sphere structure of the salts occurring in the course of thermal dehydration have been determined.

Zusammenfassung

Neue Komplexsalze der Lanthanidchloride mit Hexamethylentetramin mit der allgemeinen FormelLnCl3·2HMTA·nH2O [Ln=La, Pr, Nd, Sm, Dy, Er;HMTA — Hexamethylentetramin N4(CH2)6;n=8, 10, 12] wurden dargestellt. Die Änderungen in der Struktur der Koordinationssphäre während der thermischen Dehydration der Salze wurden mittels Infrarot-(4 000–200 cm−1) und Ramanspektroskopie (3 000–300 cm−) bestimmt.

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Authors and Affiliations

  1. Institute of General Chemistry, Polytechnical University, PL-90-924, Łódź, Poland

    Małgorzata Zalewicz

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  1. Małgorzata Zalewicz
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Zalewicz, M. Preparation and examination of properties of lanthanide chloride salts with hexamethylenetetramine. Monatsh Chem 121, 249–257 (1990). https://doi.org/10.1007/BF00808925

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  • DOI: https://doi.org/10.1007/BF00808925

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