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Decomposition of peracids and their salts with activated carbon

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Abstract

Activated carbon-mediated reductive decomposition of several commonly used peracids, peracid salts, and alkyl hydroperoxides was investigated, and oxygen release was measured. Environmentally unfriendly reagents such as dimethyl sulfide, trimethyl phosphite, and triphenyl phosphine were ineffective in reducing the peracid salts. However, the environmentally friendly and waste-minimizing activated carbon proved an effective, simple, and safe method for the decomposition of peracids, peracid salts, and alkyl hydroperoxides.

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References

  1. S. Knapp, M.J. Sebastian and H. Ramanthan, J. Org. Chem. 48 (1983) 4786.

    Google Scholar 

  2. J.K. Crandall, D.B. Banks, R.A. Colyer, R.J. Watkins and J.P. Arrington, J. Org. Chem. 33 (1968) 423.

    Google Scholar 

  3. M. Korach, D.R. Nielsen and W.H. Rideout, J. Am. Chem. Soc. 82 (1960) 4328.

    Google Scholar 

  4. C.L. Bretherick,Bretherick's Handbook of Reactive Chemical Hazards, 4th Ed. (Butterworths, London, 1991) pp. 257, 278–280, 1750–1754.

    Google Scholar 

  5. R.W. Couglin, I & EC Product Research and Development 8 (1969) 12.

    Google Scholar 

  6. S.M. Mikhalovskii, V.V. Strelko and Y.P. Butylin, Teoreticheskaya i Eksperimental'naya Khimiya 25 (1989) 366 (translated).

    Google Scholar 

  7. B. Makino, M. Kawai, T. Yamamoto, H. Yamamura, Y. Butsugan, M. Hayashi and K. Ogawa, J. Chem. Soc. Chem. Commun. 19 (1992) 1430.

    Google Scholar 

  8. J.T. Barbas and J.E. Lefller, J. Org. Chem. 50 (1985) 705.

    Google Scholar 

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Davis, R., Lovelace, T.C., Martinez, N.J. et al. Decomposition of peracids and their salts with activated carbon. Catal Lett 31, 307–311 (1995). https://doi.org/10.1007/BF00808843

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  • DOI: https://doi.org/10.1007/BF00808843

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