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Eine neue Verbindung vom M5TiB2O10-Typ mit geordneter Metallverteilung: Ni5SnB2O10

A new compound of the M5TiB2O10-type with ordered metal distribution: Ni5SnB2O10

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

The unknown compound Ni5SnB2O10, prepared by using a flux of excess B2O3, was investigated by single crystal X-ray technique. It crystallizes with orthorhombic symmetry, space group D 162h — Pnma witha=9.302,b=6.089,c=12.280 Å,Z=4. The mean result of this investigation is a hitherto unobserved strictly ordered metal distribution. Ni5SnB2O10 is not isotypic but related to Ni5TiB2O10.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Christian-Albrechts-Universität, D-2300, Kiel, Bundesrepublik Deutschland

    Karsten Bluhm & Hanskarl Müller-Buschbaum

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  1. Karsten Bluhm
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  2. Hanskarl Müller-Buschbaum
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Bluhm, K., Müller-Buschbaum, H. Eine neue Verbindung vom M5TiB2O10-Typ mit geordneter Metallverteilung: Ni5SnB2O10 . Monatsh Chem 120, 85–89 (1989). https://doi.org/10.1007/BF00808749

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  • DOI: https://doi.org/10.1007/BF00808749

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